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Merck
CN

71495

Sigma-Aldrich

Red-Al® sodium bis(2-methoxyethoxy)aluminum hydride solution

technical, ~70% in toluene (~3.5 M)

Synonym(s):

SBAH, Sodium bis(2-methoxyethoxy)aluminum dihydride, Sodium dihydrido-bis(2-methoxyethoxy)aluminate

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About This Item

Linear Formula:
NaAlH2(OCH2CH2OCH3)2
CAS Number:
22722-98-1
Molecular Weight:
202.16
MDL number:
MFCD00011631
UNSPSC Code:
12352000
PubChem Substance ID:
24886202

Key Documents

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grade

technical

expl. lim.

7 %

reaction suitability

reagent type: reductant

concentration

~70% in toluene (~3.5 M)

density

1.02 g/mL at 20 °C

SMILES string

[Na+].[H][Al-]([H])(OCCOC)OCCOC

InChI

1S/2C3H7O2.Al.Na.2H/c2*1-5-3-2-4;;;;/h2*2-3H2,1H3;;;;/q2*-1;2*+1;;

InChI key

XJIQVZMZXHEYOY-UHFFFAOYSA-N

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Other Notes

Review

Legal Information

Red-Al is a registered trademark of Merck KGaA, Darmstadt, Germany

Regulatory Information

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O. Strouf et al.
Sodium dihydrido-bis(2-methoxyethoxo)aluminate, J. Organomet. Chem. Library, 15 null
L E Pope et al.
Journal of lipid research, 37(10), 2167-2178 (1996-10-01)
The 22-carbon fatty alcohol, n-docosanol, exhibits in vitro antiviral activity against several lipid-enveloped viruses including herpes simplex viruses 1 and 2 by a mechanism that interferes with normal viral entry into target cells. We previously reported that mammalian cells incorporate
Naval Bajwa et al.
The Journal of organic chemistry, 73(9), 3638-3641 (2008-03-25)
In this paper, we have demonstrated that Red-Al is an efficient chelation-controlled reducing reagent for acyclic acetal (i.e., MOM, MEM, SEM, and BOM) protected alpha-hydroxy ketones. Typically, diastereomeric ratios (dr) ranged from 5 to 20:1 for the 1,2- anti-diols in
J Hetflejs et al.
Chemosphere, 44(6), 1521-1529 (2001-08-22)
The complete dechlorination of PCB liquid Delor 103 (42.6% Cl) to biphenyl has been effected in toluene with sodium dihydridobis(2-methoxyethoxo)aluminate (SDMA) in the presence of catalytic amounts of Ni(II) and Co(II) 2,4-pentanedionates at elevated temperatures. Changes in PCB congeners distribution

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