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Merck
CN

72070

Sodium tungstate dihydrate

puriss. p.a., ACS reagent, ≥99.0% (AT)

Synonym(s):

Tungstic acid sodium salt dihydrate

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About This Item

Linear Formula:
Na2WO4 · 2H2O
CAS Number:
Molecular Weight:
329.85
EC Number:
236-743-4
UNSPSC Code:
12352300
PubChem Substance ID:
MDL number:
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grade

ACS reagent, puriss. p.a.

assay

≥99.0% (AT)

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

impurities

≤0.001% total nitrogen (N), ≤0.05% free alkali (as NaOH)

mp

698 °C (lit.)

anion traces

chloride (Cl-): ≤50 mg/kg, sulfate (SO42-): ≤100 mg/kg

cation traces

As: ≤1 mg/kg, Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤10 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, K: ≤50 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Mo: ≤10 mg/kg, Ni: ≤10 mg/kg, Pb: ≤10 mg/kg, Zn: ≤5 mg/kg

SMILES string

O.O.[Na+].[Na+].[O-][W]([O-])(=O)=O

InChI

1S/2Na.2H2O.4O.W/h;;2*1H2;;;;;/q2*+1;;;;;2*-1;

InChI key

WPZFLQRLSGVIAA-UHFFFAOYSA-N

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Application

Catalyst for greener oxidation of alcohols and sulfides using hydrogen peroxide. Also catalyzes epoxidations and oxidative cleavage of olefins.

Noyori Oxidation (Sodium Tungstate Dihydrate, Hydrogen Peroxide, Methyltri-n-octylammonium Hydrogen Sulfate, Phosphonic Acid)

Other Notes

A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

13 - Non Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Marta Amigó-Correig et al.
PloS one, 7(7), e39087-e39087 (2012-07-18)
This study aims at exploring the effects of sodium tungstate treatment on hypothalamic plasticity, which is known to have an important role in the control of energy metabolism. Adult lean and high-fat diet-induced obese mice were orally treated with sodium
José Angel Martín Rodriguez et al.
Journal of plant physiology, 167(8), 606-613 (2010-01-19)
We examined whether the reduced mycorrhization of abscisic acid (ABA)-deficient tomato mutants correlates with their incapacity in ABA biosynthesis and whether this effect is dependent on ethylene production. The mycorrhization of notabilis and sitiens mutants, which have different ABA deficiencies
M Amigó-Correig et al.
Diabetes, obesity & metabolism, 13(3), 235-242 (2011-01-06)
Sodium tungstate is an anti-obesity drug targeting peripheral tissues. In vivo, sodium tungstate reduces body weight gain and food intake through increasing energy expenditure and lipid oxidation, but it also modulates hypothalamic gene expression when orally administered, raising the possibility
Delia Zafra et al.
FEBS letters, 587(3), 291-296 (2012-12-25)
Tungstate treatment ameliorates experimental diabetes by increasing liver glycogen deposition through an as yet unidentified mechanism. The signalling mechanism of tungstate was studied in CHOIR cells and primary cultured hepatocytes. This compound exerted its pro-glycogenic effects through a new G-protein-dependent
Andrew R Osterburg et al.
Journal of immunotoxicology, 7(3), 174-182 (2010-02-25)
The potential for adverse health effects of using tungsten and its alloys in military munitions are an important concern to both civilians and the US military. The toxicological implications of exposure to tungsten, its alloys, and the soluble tungstate (Na(2)WO(4))

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