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Merck
CN

72070

Sodium tungstate dihydrate

puriss. p.a., ACS reagent, ≥99.0% (AT)

Synonym(s):

Tungstic acid sodium salt dihydrate

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About This Item

Linear Formula:
Na2WO4 · 2H2O
CAS Number:
Molecular Weight:
329.85
EC Number:
236-743-4
UNSPSC Code:
12352300
PubChem Substance ID:
MDL number:
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InChI key

WPZFLQRLSGVIAA-UHFFFAOYSA-N

InChI

1S/2Na.2H2O.4O.W/h;;2*1H2;;;;;/q2*+1;;;;;2*-1;

SMILES string

O.O.[Na+].[Na+].[O-][W]([O-])(=O)=O

grade

ACS reagent, puriss. p.a.

assay

≥99.0% (AT)

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

impurities

≤0.001% total nitrogen (N), ≤0.05% free alkali (as NaOH)

mp

698 °C (lit.)

anion traces

chloride (Cl-): ≤50 mg/kg, sulfate (SO42-): ≤100 mg/kg

cation traces

As: ≤1 mg/kg, Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤10 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, K: ≤50 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Mo: ≤10 mg/kg, Ni: ≤10 mg/kg, Pb: ≤10 mg/kg, Zn: ≤5 mg/kg

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Application

Catalyst for greener oxidation of alcohols and sulfides using hydrogen peroxide. Also catalyzes epoxidations and oxidative cleavage of olefins.

Noyori Oxidation (Sodium Tungstate Dihydrate, Hydrogen Peroxide, Methyltri-n-octylammonium Hydrogen Sulfate, Phosphonic Acid)

Other Notes

A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

13 - Non Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Marta Amigó-Correig et al.
PloS one, 7(7), e39087-e39087 (2012-07-18)
This study aims at exploring the effects of sodium tungstate treatment on hypothalamic plasticity, which is known to have an important role in the control of energy metabolism. Adult lean and high-fat diet-induced obese mice were orally treated with sodium
José Angel Martín Rodriguez et al.
Journal of plant physiology, 167(8), 606-613 (2010-01-19)
We examined whether the reduced mycorrhization of abscisic acid (ABA)-deficient tomato mutants correlates with their incapacity in ABA biosynthesis and whether this effect is dependent on ethylene production. The mycorrhization of notabilis and sitiens mutants, which have different ABA deficiencies
Josie E Bamford et al.
Environmental toxicology and chemistry, 30(10), 2312-2318 (2011-08-02)
Due to unknown effects of the potential exposure of the terrestrial environment to tungsten substances, a series of toxicity studies of sodium tungstate (Na(2) WO(4) ) was conducted. The effect on earthworm (Eisenia fetida) survival and reproduction was examined using
M Milagros Gómez-Gómez et al.
Talanta, 84(4), 1011-1018 (2011-05-03)
It is known that oral administration of sodium tungstate preserves the pancreatic beta cell function in diabetic rats. Healthy and streptozotocin-induced diabetic rats were treated with sodium tungstate for one, three or six weeks, after which the species of W
M Amigó-Correig et al.
Diabetes, obesity & metabolism, 13(3), 235-242 (2011-01-06)
Sodium tungstate is an anti-obesity drug targeting peripheral tissues. In vivo, sodium tungstate reduces body weight gain and food intake through increasing energy expenditure and lipid oxidation, but it also modulates hypothalamic gene expression when orally administered, raising the possibility

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