73210
4-(4-Nitrobenzyl)pyridine
for spectrophotometric det. of phosphorus-containing pesticides
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About This Item
Empirical Formula (Hill Notation):
C12H10N2O2
CAS Number:
Molecular Weight:
214.22
UNSPSC Code:
12352200
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-108-2
Beilstein/REAXYS Number:
170877
MDL number:
InChI
1S/C12H10N2O2/c15-14(16)12-3-1-10(2-4-12)9-11-5-7-13-8-6-11/h1-8H,9H2
InChI key
MNHKUCBXXMFQDM-UHFFFAOYSA-N
SMILES string
[O-][N+](=O)c1ccc(Cc2ccncc2)cc1
assay
≥98.0% (NT)
form
crystals
quality
for spectrophotometric det. of phosphorus-containing pesticides
technique(s)
thin layer chromatography (TLC): suitable
ign. residue
≤0.1%
mp
69-71 °C (lit.)
Quality Level
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Application
for the detection of epoxides and methylating reagents; for spectrophotometric determination of phosphorus-containing pesticides
Other Notes
Reagent for the determination of alkylating agents
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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G.W. Fischer
Analytica Chimica Acta, 92, 149-149 (1977)
Studies on chemical carcinogens. XXIII. A simple method for characterization of the alkylating ability of compounds by using 4-(p-nitrobenzyl)-pyridine.
Y Kawazoe et al.
Chemical & pharmaceutical bulletin, 30(6), 2077-2086 (1982-06-01)
Spectrophotometric determination of organophosphorus pesticides with 4-(4-nitrobenzyl)pyridine.
C R Turner
The Analyst, 99(180), 431-434 (1974-07-01)
Marina González-Pérez et al.
Chemical research in toxicology, 25(12), 2755-2762 (2012-11-23)
The chemical reactivity of the mutagenic epoxides (EP) propylene oxide (PO), 1,2-epoxybutane (1,2-EB), and cis- and trans-2,3-epoxybutane (cis- and trans-2,3-EB) with 4-(p-nitrobenzyl)pyridine (NBP), a bionucleophile model for S(N)2 alkylating agents with high affinity for the guanine-N7 position, was investigated kinetically.
Rafael Gómez-Bombarelli et al.
Environmental science & technology, 45(20), 9009-9016 (2011-09-14)
Hydroxyhalofuranones form a group of genotoxic disinfection byproduct (DBP) of increasing interest. Among them, mucohalic acids (3,4-dihalo-5-hydroxyfuran-2(5H)-one, MXA) are known mutagens that react with nucleotides, affording etheno, oxaloetheno, and halopropenal derivatives. Mucohalic acids have also found use in organic synthesis
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