73325
Methyl nitroacetate
purum, ≥97.0% (GC)
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About This Item
Linear Formula:
NO2CH2COOCH3
CAS Number:
Molecular Weight:
119.08
EC Number:
219-622-0
UNSPSC Code:
12352100
MDL number:
Beilstein/REAXYS Number:
1758670
grade
purum
assay
≥97.0% (GC)
refractive index
n20/D 1.425 (lit.), n20/D 1.426
bp
195-198 °C (lit.)
density
1.294 g/mL at 25 °C (lit.)
SMILES string
COC(=O)C[N+]([O-])=O
InChI
1S/C3H5NO4/c1-8-3(5)2-4(6)7/h2H2,1H3
InChI key
ALBSWLMUHHZLLR-UHFFFAOYSA-N
Other Notes
Use in organic synthesis, a review; Synthesis of 2,5-dioxoalkanoates from enones
Disclaimer
may discolor to yellow on storage
Regulatory Information
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M.T. Shipchandler
Synthesis, 666-666 (1979)
W.J. Thompson et al.
The Journal of Organic Chemistry, 48, 2769-2769 (1983)
Benoît Moreau et al.
Journal of the American Chemical Society, 127(51), 18014-18015 (2005-12-22)
A highly enantioselective (up to 97.5% ee) and diastereoselective (95:5 dr trans/cis) Cu(I)-catalyzed cyclopropanation of alkenes using phenyliodonium ylide generated in situ from iodosobenzene and methyl nitroacetate is reported. The cyclopropanation took place with high enantioselectivity for a wide range
[Experimental establishment of the maximum permissible concentration of the methyl and ethyl esters of nitroacetic acid].
G I Sidorin et al.
Gigiena truda i professional'nye zabolevaniia, (7)(7), 49-51 (1980-07-01)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 4160-100GM | 04055977187779 |
| 1053579010 | 04022536906904 |
| 1053620100 | 04022536063539 |
| 8160080025 | 04022536423500 |
| 8160080010 | 04022536423494 |
| W527602-100G | 04061835567713 |
| PHR1099-1G | 04061835237319 |
| I5281-25KG | 04061834432388 |
| I5281-1KG | 04061833857250 |
| I5281-10KG | 04061834415565 |
| I7403-25G | 04061833858264 |
| I7403-1KG | 04061826756393 |
| I0460000 | 04061833811856 |
| I2752-100G | 04061835361373 |
| I2752-25G | 04061835361410 |
| 1349502-200MG | 04061838730374 |
| 1053620025 | 04022536063522 |
| 1053571000 | 04022536906898 |
| 1053629010 | 04022536692739 |
| 1053620500 | 04022536063546 |
| 56241-1G | 04061834232896 |
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