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Merck
CN

74886

Supelco

Sodium 1-octanesulfonate solution

suitable for ion pair chromatography, LiChropur, concentrate, ampule

Synonym(s):

1-Octanesulfonic acid sodium salt

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About This Item

Linear Formula:
CH3(CH2)6CH2SO3Na
CAS Number:
Molecular Weight:
216.27
Beilstein:
3574241
MDL number:
UNSPSC Code:
41115710
PubChem Substance ID:
NACRES:
NB.21
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Quality Level

form

liquid

quality

LiChropur
ampule

packaging

ampule of 25 mL

technique(s)

ion pair chromatography: suitable

λ

in concentrate

UV absorption

λ: 210 nm Amax: 0.08
λ: 220 nm Amax: 0.05
λ: 230 nm Amax: 0.03
λ: 260 nm Amax: 0.02
λ: 500 nm Amax: 0.02

suitability

corresponds to standard for RP gradient test
corresponds to standard for filter test

SMILES string

[Na+].CCCCCCCCS([O-])(=O)=O

InChI

1S/C8H18O3S.Na/c1-2-3-4-5-6-7-8-12(9,10)11;/h2-8H2,1H3,(H,9,10,11);/q;+1/p-1

InChI key

HRQDCDQDOPSGBR-UHFFFAOYSA-M

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General description

Concentrate for 6x1 L ready-to-use solution. Dilute contents of one ampule (~0.3 M) to 1 L with HPLC grade water to obtain a 0.005 M eluent solution.
Sodium 1-octanesulfonate monohydrate (NaOS) is an ion-pairing reagent.

Application

NaOS has been used as ion-pairing reagent for ultra-high performance liquid chromatography (UPLC) analysis with photodiode array detection to estimate paraquat (methyl viologen) in tissue homogenate. It may also be used in determination of dopamine and its metabolites in brain microdialysates using liquid chromatography combined with electrospray ionization tandem mass spectrometry (LC–ESI-MS/MS).

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Rapid and simple analysis of paraquat in tissue homogenate by ultra-high performance liquid chromatography.
Merritt, T. J. S., et al.
Analytical Methods : Advancing Methods and Applications, 3.6, 1428-1432 (2011)
Kamila Syslová et al.
Journal of chromatography. A, 1218(21), 3382-3391 (2011-03-15)
A sensitive assay method was developed for a parallel, rapid and precise determination of dopamine and its metabolites, homovanillic acid, 3-methoxytyramine and 3,4-dihydroxyphenylacetic acid, from brain microdialysates. The method consisted of a pre-treatment step, freeze-drying (lyophilization), to concentrate dopamine and
Xin Su et al.
Chemical communications (Cambridge, England), 49(26), 2655-2657 (2013-02-26)
We report two CO2-responsive aqueous solutions having switchable viscosity. The solution of sodium octadecyl sulfate and 2-(dimethylamino)ethanol forms viscoelastic worm-like micelles in the presence of CO2 but not in its absence at 60 °C. Another solution of sodium stearate and
P G Jaison et al.
Journal of chromatography. A, 1216(9), 1383-1389 (2009-01-27)
Studies were carried out for the separation of uranium (U) and thorium (Th) on reversed-phase (RP) C18 columns using mandelic acid as an eluent. Retention of thorium-mandelate on the unmodified stationary phase was found to be greater than that of
J L Razak et al.
Pharmaceutical research, 18(1), 104-111 (2001-05-05)
The aim of this study was to develop a method based upon electrokinetic chromatography (EKC) using oppositely charged surfactant vesicles as a buffer modifier to estimate hydrophobicity (log P) for a range of neutral and charged compounds. Vesicles were formed

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