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Merck
CN

75552

Fenhexamid-(methyl-d3)

PESTANAL®, analytical standard

Synonym(s):

N-(2,3-Dichloro-4-hydroxyphenyl)-1-methyl-d3-cyclohexanecarboxamide, Fenhexamid-d3

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About This Item

Empirical Formula (Hill Notation):
C14D3H14Cl2NO2
Molecular Weight:
305.21
UNSPSC Code:
12352200
PubChem Substance ID:
NACRES:
NA.24
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grade

analytical standard

Quality Level

product line

PESTANAL®

assay

≥98.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

application(s)

agriculture

format

neat

storage temp.

2-8°C

SMILES string

O=C(NC1=C(Cl)C(Cl)=C(O)C=C1)C2(C([2H])([2H])[2H])CCCCC2

General description

Fenhexamid-(methyl-d3) is an isotope-labeled analog of the hydroxyanilide fungicide fenhexamid, wherein all the methyl protons are replaced by deuterium.

Application

Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The main advantage of using the IDMS technique is because isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analog, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany


pictograms

Environment

hcodes

Hazard Classifications

Aquatic Chronic 2

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Baseline sensitivity of Monilinia laxa from Greece to fenhexamid and analysis of fenhexamid-resistant mutants
Malandrakis A, et al.
Crop Protection, 46, 13-17 (2013)



Global Trade Item Number

SKUGTIN
75552-5MG04061832908892