77847
(R)-(−)-1-Phenyl-1,2-ethanediol
purum, ≥98.0% (sum of enantiomers, HPLC)
Synonym(s):
(−)-Styrene glycol, (R)-(−)-Phenylethylene glycol
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About This Item
Linear Formula:
HOCH2CH(C6H5)OH
CAS Number:
Molecular Weight:
138.16
PubChem Substance ID:
UNSPSC Code:
12352002
Beilstein/REAXYS Number:
2355547
MDL number:
SMILES string
OC[C@H](O)c1ccccc1
InChI
1S/C8H10O2/c9-6-8(10)7-4-2-1-3-5-7/h1-5,8-10H,6H2/t8-/m0/s1
InChI key
PWMWNFMRSKOCEY-QMMMGPOBSA-N
grade
purum
assay
≥98.0% (sum of enantiomers, HPLC)
optical activity
[α]/D −69±4°, c = 1 in chloroform
bp
272-274 °C (lit.)
mp
64-67 °C (lit.)
Other Notes
Chiral building block used in various syntheses
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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G. Lowe et al.
Journal of the Chemical Society. Chemical Communications, 466-466 (1984)
R.B. King et al.
The Journal of Organic Chemistry, 44, 1729-1729 (1979)
B.B. Lohray et al.
Journal of the Chemical Society. Chemical Communications, 95-95 (1991)
J.S. Bradshaw et al.
The Journal of Organic Chemistry, 47, 1229-1229 (1982)
Lingyun Rui et al.
Applied and environmental microbiology, 71(7), 3995-4003 (2005-07-08)
DNA shuffling and saturation mutagenesis of positions F108, L190, I219, D235, and C248 were used to generate variants of the epoxide hydrolase of Agrobacterium radiobacter AD1 (EchA) with enhanced enantioselectivity and activity for styrene oxide and enhanced activity for 1,2-epoxyhexane
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