78178
Lithium tri-sec-butylborohydride solution
~1 M in THF
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About This Item
Linear Formula:
Li[CH(CH3)CH2CH3]3BH
CAS Number:
Molecular Weight:
190.10
UNSPSC Code:
12352103
Beilstein/REAXYS Number:
4007327
MDL number:
InChI
1S/C12H28B.Li/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h10-13H,7-9H2,1-6H3;/q-1;+1
SMILES string
[Li+].[H][B-](C(C)CC)(C(C)CC)C(C)CC
InChI key
ACJKNTZKEFMEAK-UHFFFAOYSA-N
concentration
~1 M in THF
density
0.89 g/mL at 20 °C (lit.)
Application
- Reducing agent
Reagent for:
- Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters
- Diastereoselective reduction reactions
- Hydride reduction of the Danishefsky pyranones
- Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes
- Synthesis of alkanols by carbonylation reactions
Legal Information
Selectride is a registered trademark of Merck KGaA, Darmstadt, Germany
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