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78590

D-(−)-α-Phenylglycinol

Name: <SC>D</SC>-(−)-α-Phenylglycinol
Brand: SIAL

purum, ≥98.0% (sum of enantiomers, HPLC)

Synonym(s):

(R)-2-Amino-2-phenylethanol

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About This Item

Empirical Formula (Hill Notation):

C₈H₁₁NO

CAS Number:

56613-80-0

Molecular Weight:

137.18

PubChem Substance ID:

24887331

UNSPSC Code:

12352200

EC Number:

260-287-5

MDL number:

MFCD00008062

Beilstein/REAXYS Number:

2935848

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Properties

grade

purum

assay

≥98.0% (sum of enantiomers, HPLC)

optical activity

[α]20/D −25.5±1°, c = 6% in methanol

optical purity

enantiomeric ratio: ≥99:1 (HPLC)

mp

76-79 °C

SMILES string

N[C@@H](CO)c1ccccc1

Description

Other Notes

Chiral hydroxy amine used for the resolution of acids via their amides which are mildly hydrolyzed by neighbouring-group participation ; chiral auxiliary

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M.A. Tschantz et al.

Organic Syntheses, 73, 221-221 (1996)

M. Bonine et al.

Organic Syntheses, 70, 54-54 (1992)

L. Strekowski et al.

The Journal of Organic Chemistry, 51, 4836-4836 (1986)