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Merck
CN

78672

Phenylhydrazine

purum, ≥95.0% (GC)

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About This Item

Linear Formula:
C6H5NHNH2
CAS Number:
100-63-0
Molecular Weight:
108.14
EC Number:
202-873-5
UNSPSC Code:
12352100
PubChem Substance ID:
329768171
Beilstein/REAXYS Number:
606080
MDL number:
MFCD00007573

Key Documents

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InChI key

HKOOXMFOFWEVGF-UHFFFAOYSA-N

InChI

1S/C6H8N2/c7-8-6-4-2-1-3-5-6/h1-5,8H,7H2

SMILES string

NNc1ccccc1

vapor density

4.3 (vs air)

vapor pressure

<0.1 mmHg ( 20 °C)

grade

purum

assay

≥95.0% (GC)

autoignition temp.

345 °F

refractive index

n20/D 1.607 (lit.)

bp

238-241 °C (lit.)

mp

18-21 °C (lit.)

density

1.098 g/mL at 25 °C (lit.)

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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

192.2 °F - closed cup

flash_point_c

89 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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M D Shetlar et al.
Environmental health perspectives, 64, 265-281 (1985-12-01)
It is well known that phenylhydrazine induces hemolytic anemia. This is thought to result from the reaction of phenylhydrazine with hemoglobin. The accompanying oxidation of phenylhydrazine leads to the formation of a number of products, including benzene, nitrogen, hydrogen peroxide
Ahmed A Ibrahim et al.
Talanta, 93, 257-263 (2012-04-10)
We report here the fabrication of a robust, highly sensitive, reliable and reproducible phenyl hydrazine chemical sensor using Ag-doped ZnO nanoflowers as efficient electron mediators. The Ag-doped ZnO nanoflowers were synthesized by facile hydrothermal process at low-temperature and characterized in
Denham G Cook et al.
The Journal of experimental biology, 214(Pt 17), 2927-2934 (2011-08-13)
The effect of altered oxygen transport potential on behavioural responses to environmental hypoxia was tested experimentally in snapper, Pagrus auratus, treated with a haemolytic agent (phenylhydrazine) or a sham protocol. Standard metabolic rate was not different between anaemic and normocythaemic
David M Frazer et al.
British journal of haematology, 157(5), 615-626 (2012-03-28)
The BMP/SMAD signalling pathway plays an important role in iron homeostasis, regulating hepcidin expression in response to body iron levels. However, the role of this pathway in the reduction in hepcidin associated with increased erythropoiesis (and secondary iron loading) is
Weiwei Huang et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 79(3), 471-475 (2011-05-03)
A novel colorimetric anion-chemosensor based on 1,10-phenanthroline-2,9-dicarbonyl-p-nitro-phenylhydrazine has been synthesized. Among the different anions tested, it shows the best selectivity towards AcO(-). The addition of acetate causes the color to change from yellow to red, which could be detected with
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