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Merck
CN

78672

Sigma-Aldrich

Phenylhydrazine

purum, ≥95.0% (GC)

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About This Item

Linear Formula:
C6H5NHNH2
CAS Number:
100-63-0
Molecular Weight:
108.14
Beilstein:
606080
EC Number:
202-873-5
MDL number:
MFCD00007573
UNSPSC Code:
12352100
PubChem Substance ID:
329768171

Key Documents

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vapor density

4.3 (vs air)

vapor pressure

<0.1 mmHg ( 20 °C)

grade

purum

Assay

≥95.0% (GC)

autoignition temp.

345 °F

refractive index

n20/D 1.607 (lit.)

bp

238-241 °C (lit.)

mp

18-21 °C (lit.)

density

1.098 g/mL at 25 °C (lit.)

SMILES string

NNc1ccccc1

InChI

1S/C6H8N2/c7-8-6-4-2-1-3-5-6/h1-5,8H,7H2

InChI key

HKOOXMFOFWEVGF-UHFFFAOYSA-N

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Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

192.2 °F - closed cup

Flash Point(C)

89 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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M D Shetlar et al.
Environmental health perspectives, 64, 265-281 (1985-12-01)
It is well known that phenylhydrazine induces hemolytic anemia. This is thought to result from the reaction of phenylhydrazine with hemoglobin. The accompanying oxidation of phenylhydrazine leads to the formation of a number of products, including benzene, nitrogen, hydrogen peroxide
Jeanne E Hendrickson et al.
Transfusion, 51(11), 2445-2454 (2011-05-17)
Fourteen-day stored red blood cells (RBCs) containing an RBC-specific transgenic antigen (HOD) induce a recipient proinflammatory cytokine storm and are significantly more immunogenic compared to fresh RBCs. Given that recipient mice clear transfused stored RBCs more rapidly than fresh RBCs
David M Frazer et al.
British journal of haematology, 157(5), 615-626 (2012-03-28)
The BMP/SMAD signalling pathway plays an important role in iron homeostasis, regulating hepcidin expression in response to body iron levels. However, the role of this pathway in the reduction in hepcidin associated with increased erythropoiesis (and secondary iron loading) is
Weiwei Huang et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 79(3), 471-475 (2011-05-03)
A novel colorimetric anion-chemosensor based on 1,10-phenanthroline-2,9-dicarbonyl-p-nitro-phenylhydrazine has been synthesized. Among the different anions tested, it shows the best selectivity towards AcO(-). The addition of acetate causes the color to change from yellow to red, which could be detected with
Soumya Maity et al.
Journal of physiology and biochemistry, 69(3), 467-476 (2013-01-16)
The ability of ethanol extract of Phyllanthus amarus root (EEPA) to decrease bilirubin level and oxidative stress in phenylhydrazine-induced neonatal jaundice in mice was investigated. Administration of phenylhydrazine (75 mg/kg b.w.) significantly elevated total and unconjugated serum bilirubin level compared
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