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78815

Methyl (phenylthio)acetate

Name: Methyl (phenylthio)acetate
Brand: SIAL

purum, ≥97.0% (GC)

Synonym(s):

Methyl (phenylmercapto)acetate

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About This Item

Linear Formula:

C₆H₅SCH₂COOCH₃

CAS Number:

17277-58-6

Molecular Weight:

182.24

UNSPSC Code:

12352103

MDL number:

MFCD00039805

Beilstein/REAXYS Number:

2047554

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Properties

grade

purum

assay

≥97.0% (GC)

refractive index

n20/D 1.559

bp

78-80 °C/0.1 mmHg

SMILES string

COC(=O)CSc1ccccc1

Description

Other Notes

More acidic derivative of methyl acetate (pK_a in DMSO: 21.4); 1,4-Addition to enones or nitroolefins

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Tetrahedron Letters, 23, 3513-3513 (1982)

P. Barbier et al.

Tetrahedron Letters, 23, 3511-3511 (1982)

S. Yamagiwa et al.

Bulletin of the Chemical Society of Japan, 51, 3011-3011 (1978)

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