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Merck
CN

79264

Triethylsilyl methallylsulfinate

Synonym(s):

2-Methyl-2-propenesulfinic acid triethylsilyl ester, SILMAS-TES, Triethylsilyl 2-methyl-2-propenesulfinate

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About This Item

Empirical Formula (Hill Notation):
C10H22O2SSi
CAS Number:
850418-19-8
Molecular Weight:
234.43
UNSPSC Code:
12352200
PubChem Substance ID:
329768353
MDL number:
MFCD18783100

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InChI

1S/C10H22O2SSi/c1-6-14(7-2,8-3)12-13(11)9-10(4)5/h4,6-9H2,1-3,5H3

SMILES string

CC[Si](CC)(CC)OS(=O)CC(C)=C

InChI key

IINRMKPFRWLCIW-UHFFFAOYSA-N

grade

derivatization grade ((GC derivatization))

assay

≥85% (GC)

reaction suitability

reagent type: derivatization reagent
reaction type: Silylations

storage temp.

2-8°C

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
BCBP1454V

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Silyl methallylsulfinates: efficient and powerful agents for the chemoselective silylation of alcohols, polyols, phenols and carboxylic acids.
Huang, X., et al.
Chemical Communications (Cambridge, England), 14, 1297-1299 (2005)

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