80219
1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Heptadecafluoro-10-iododecane
purum, >95.0% (GC)
Synonym(s):
1-Iodo-1H,1H,2H,2H-perfluorodecane, 1H,1H,2H,2H-Perfluoro-1-decyl iodide
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About This Item
Linear Formula:
CF3(CF2)7CH2CH2I
CAS Number:
Molecular Weight:
574.02
EC Number:
218-053-5
UNSPSC Code:
12352200
PubChem Substance ID:
Beilstein/REAXYS Number:
1894667
MDL number:
grade
purum
assay
>95.0% (GC)
mp
54-58 °C
SMILES string
FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCI
InChI
1S/C10H4F17I/c11-3(12,1-2-28)4(13,14)5(15,16)6(17,18)7(19,20)8(21,22)9(23,24)10(25,26)27/h1-2H2
InChI key
XVKJSLBVVRCOIT-UHFFFAOYSA-N
Other Notes
Preparation of new highly fluorophilic ligands for fluorous biphase catalysis
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T. Briza et al.
Tetrahedron, 58, 3841-3841 (2002)
David Crich et al.
Organic letters, 4(23), 4175-4177 (2002-11-09)
Borane gas and 2-(perfluorooctyl)ethyl methyl sulfide form a solid comprised of an approximately 1:1 mixture (fluorous BMS) of sulfide and the corresponding sulfide-borane. Fluorous BMS permits hydroboration of alkenes in a dichloromethane/perfluorinated hydrocarbon mixture with subsequent recycling of the fluorous
Repetitive Application of Perfluoro-Tagged Pd Complexes for Stille Couplings in a Fluorous Biphasic System This work was supported by Fluka (Buchs) and Byk Gulden Pharmaceuticals (Konstanz). S.S. thanks Fluka for financial support. We would also thank Priv.-Doz. Dr. C. Rücker for help in the preparation of the manuscript.
Schneider et al.
Angewandte Chemie (International ed. in English), 39(22), 4142-4145 (2000-11-28)
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