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Merck
CN

80903

Pivalic anhydride

purum, ≥98.0% (GC)

Synonym(s):

2,2-Dimethylpropionic anhydride

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About This Item

Linear Formula:
[(CH3)3CCO]2O
CAS Number:
1538-75-6
Molecular Weight:
186.25
EC Number:
216-263-1
UNSPSC Code:
12352100
PubChem Substance ID:
24887588
Beilstein/REAXYS Number:
386552
MDL number:
MFCD00008842

Key Documents

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InChI key

PGZVFRAEAAXREB-UHFFFAOYSA-N

InChI

1S/C10H18O3/c1-9(2,3)7(11)13-8(12)10(4,5)6/h1-6H3

SMILES string

CC(C)(C)C(=O)OC(=O)C(C)(C)C

grade

purum

assay

≥98.0% (GC)

refractive index

n20/D 1.409 (lit.), n20/D 1.409

bp

193 °C (lit.)

density

0.918 g/mL at 25 °C (lit.)

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Other Notes

This product has been replaced by 143502-ALDRICH | Trimethylacetic anhydride 99%

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

162.5 °F - closed cup

flash_point_c

72.5 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Isamu Shiina et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(1), 167-172 (2009-11-12)
A variety of optically active 2-hydroxyalkanoates and the corresponding 2-acyloxyalkanoates are produced by the kinetic resolution of racemic 2-hydroxyalkanoates by using achiral 2,2-diarylacetic acid with hindered carboxylic anhydrides as the coupling reagents. The combined use of diphenylacetic acid, pivalic anhydride
M Joppich et al.
Analytical biochemistry, 153(1), 159-165 (1986-02-15)
Reaction of thyroxine with ethanol and pivalic anhydride in the presence of 4-dimethylaminopyridine quantitatively forms N,O-dipivalyl thyroxine ethyl ester. Other iodothyronines react similarly and the procedure is moisture insensitive. Apparently this reaction is successful, in contrast to similar procedures reported

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