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Merck
CN

81844

Sigma-Aldrich

Trimethyl(propargyl)silane

technical, ~85% (GC)

Synonym(s):

2-Propynyl-trimethylsilane, 3-(Trimethylsilyl)propyne

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About This Item

Linear Formula:
HC≡CCH2Si(CH3)3
CAS Number:
Molecular Weight:
112.24
Beilstein:
2036316
MDL number:
UNSPSC Code:
12352100
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grade

technical

Assay

~85% (GC)

contains

~0.5% 2,6-di-tert-butyl-4-methylphenol as stabilizer

impurities

~10% isomeric allenyltrimethylsilane in equilibrium

refractive index

n20/D 1.413 (lit.)
n20/D 1.413

bp

91-93 °C (lit.)

density

0.753 g/mL at 25 °C (lit.)

shipped in

wet ice

storage temp.

−20°C

SMILES string

C[Si](C)(C)CC#C

InChI

1S/C6H12Si/c1-5-6-7(2,3)4/h1H,6H2,2-4H3

InChI key

ULYLMHUHFUQKOE-UHFFFAOYSA-N

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Other Notes

Equilibrium with allenyl-trimethylsilane; Starting material for preparing substituted propargyl-silanes; these are used for the Lewis acid-catalyzed introduction of allenyl groups in electrophiles; Selective preparation of (E)- and (Z)-olefins

Pictograms

FlameExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

23.0 °F - closed cup

Flash Point(C)

-5 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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J. Slutsky et al.
Journal of the American Chemical Society, 95, 8678-8678 (1973)
P.M. Esch et al.
Tetrahedron Letters, 29, 367-367 (1988)
J. Pornet et al.
Journal of Organometallic Chemistry, 349, 43-43 (1988)
A.G. Angoh et al.
Journal of the Chemical Society. Chemical Communications, 534-534 (1985)
H. Hiemstra et al.
The Journal of Organic Chemistry, 50, 4014-4014 (1985)

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