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Merck
CN

82227

Propylene carbonate

Selectophore™, ≥99.0%

Synonym(s):

1,2-Propanediol cyclic carbonate, 4-Methyl-1,3-dioxolan-2-one

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About This Item

Empirical Formula (Hill Notation):
C4H6O3
CAS Number:
108-32-7
Molecular Weight:
102.09
UNSPSC Code:
26111700
NACRES:
NB.61
PubChem Substance ID:
329769239
EC Number:
203-572-1
Beilstein/REAXYS Number:
107913
MDL number:
MFCD00005385
Assay:
≥99.0% (GC), ≥99.0%
Bp:
240 °C (lit.)
Vapor pressure:
0.13 mmHg ( 20 °C), 0.98 mmHg ( 50 °C)

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InChI key

RUOJZAUFBMNUDX-UHFFFAOYSA-N

InChI

1S/C4H6O3/c1-3-2-6-4(5)7-3/h3H,2H2,1H3

SMILES string

CC1COC(=O)O1

vapor pressure

0.13 mmHg ( 20 °C), 0.98 mmHg ( 50 °C)

description

for ion-selective electrodes, solvent for preparation of membranes

product line

Selectophore™

assay

≥99.0% (GC), ≥99.0%

form

liquid

autoignition temp.

851 °F

expl. lim.

14.3 %

Quality Level

200

refractive index

n20/D 1.423

bp

240 °C (lit.)

mp

−55 °C (lit.)

density

1.204 g/mL at 25 °C (lit.)

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General description

Propylene carbonate (PC) is an organic amide compound generally used as solvent in organic electrochemistry. It is considered as a high-permittivity component of electrolytes.
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Application

It has been used to exfoliate graphite oxide by bath sonication. It has also been used to prepare 1M lithium perchlorate, which served as electrolyte in measurement of thin-film of orthorhombic Niobium pentoxide (Nb2O5).

Legal Information

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H319

Hazard Classifications

Eye Irrit. 2

Storage Class

10 - Combustible liquids

wgk

WGK 1

flash_point_f

269.6 °F - closed cup

flash_point_c

132 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
BCCD4676
233687/1

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High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance.
Augustyn, Veronica, et al.
Nature Materials, 12.6, 518-522 (2013)
Ole Hammerich, Henning Lund
Organic Electrochemistry, 1416-1416 (2000)
Exfoliation of graphite oxide in propylene carbonate and thermal reduction of the resulting graphene oxide platelets.
Zhu, Yanwu, et al.
ACS Nano, 4.2, 1227-1233 (2010)
Carbonates: ecofriendly solvents for palladium-catalyzed direct 2-arylation of oxazole derivatives.
Julien Roger et al.
ChemSusChem, 2(10), 951-956 (2009-10-07)
Yingying Lu et al.
Advanced materials (Deerfield Beach, Fla.), 24(32), 4430-4435 (2012-07-13)
Ionic liquid-tethered nanoparticle hybrid electrolytes comprised of silica nanoparticles densely grafted with imidazolium-based ionic liquid chains are shown to retard lithium dendrite growth in rechargeable batteries with metallic lithium anodes. The electrolytes are demonstrated in full cell studies using both
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