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Merck
CN

82227

Propylene carbonate

Selectophore™, ≥99.0%

Synonym(s):

1,2-Propanediol cyclic carbonate, 4-Methyl-1,3-dioxolan-2-one

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About This Item

Empirical Formula (Hill Notation):
C4H6O3
CAS Number:
108-32-7
Molecular Weight:
102.09
UNSPSC Code:
26111700
NACRES:
NB.61
PubChem Substance ID:
329769239
EC Number:
203-572-1
Beilstein/REAXYS Number:
107913
MDL number:
MFCD00005385
Assay:
≥99.0% (GC)
≥99.0%
Bp:
240 °C (lit.)
Vapor pressure:
0.13 mmHg ( 20 °C)
0.98 mmHg ( 50 °C)

Key Documents

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Product Name

Propylene carbonate, Selectophore™, ≥99.0%

InChI key

RUOJZAUFBMNUDX-UHFFFAOYSA-N

InChI

1S/C4H6O3/c1-3-2-6-4(5)7-3/h3H,2H2,1H3

SMILES string

CC1COC(=O)O1

vapor pressure

0.13 mmHg ( 20 °C)
0.98 mmHg ( 50 °C)

description

for ion-selective electrodes
solvent for preparation of membranes

product line

Selectophore™

assay

≥99.0% (GC)
≥99.0%

form

liquid

autoignition temp.

851 °F

expl. lim.

14.3 %

refractive index

n20/D 1.421 (lit.)
n20/D 1.423

bp

240 °C (lit.)

mp

−55 °C (lit.)

density

1.204 g/mL at 25 °C (lit.)

Quality Level

200

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Application

It has been used to exfoliate graphite oxide by bath sonication. It has also been used to prepare 1M lithium perchlorate, which served as electrolyte in measurement of thin-film of orthorhombic Niobium pentoxide (Nb2O5).

General description

Propylene carbonate (PC) is an organic amide compound generally used as solvent in organic electrochemistry. It is considered as a high-permittivity component of electrolytes.
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Legal Information

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H319

Hazard Classifications

Eye Irrit. 2

Storage Class

10 - Combustible liquids

wgk

WGK 1

flash_point_f

269.6 °F - closed cup

flash_point_c

132 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
BCCD4676
233687/1

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High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance.
Augustyn, Veronica, et al.
Nature Materials, 12.6, 518-522 (2013)
Ole Hammerich, Henning Lund
Organic Electrochemistry, 1416-1416 (2000)
Exfoliation of graphite oxide in propylene carbonate and thermal reduction of the resulting graphene oxide platelets.
Zhu, Yanwu, et al.
ACS Nano, 4.2, 1227-1233 (2010)
M V Kondrin et al.
The Journal of chemical physics, 137(8), 084502-084502 (2012-09-04)
We present the high pressure dielectric spectroscopy (up to 4.2 GPa) and ultrasonic study (up to 1.7 GPa) of liquid and glassy propylene carbonate (PC). Both of the methods provide complementary pictures of the glass transition in PC under pressure.
Carbonates: ecofriendly solvents for palladium-catalyzed direct 2-arylation of oxazole derivatives.
Julien Roger et al.
ChemSusChem, 2(10), 951-956 (2009-10-07)
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