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Merck
CN

83725

Rhodium(II) acetate dimer dihydrate

purum, ~43% rhodium (Rh) basis

Synonym(s):

Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)

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About This Item

Linear Formula:
[Rh(CH3COO)2]2 · 2H2O
CAS Number:
Molecular Weight:
478.02
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
240-084-8
MDL number:
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InChI key

SYBXSZMNKDOUCA-UHFFFAOYSA-J

InChI

1S/4C2H4O2.2Rh/c4*1-2(3)4;;/h4*1H3,(H,3,4);;/q;;;;2*+2/p-4

SMILES string

CC(=O)O[Rh]OC(C)=O.CC(=O)O[Rh]OC(C)=O

grade

purum

reaction suitability

reagent type: catalyst
core: rhodium

concentration

~43% Rh

Other Notes

Efficient catalyst for the cyclopropanation of olefins by diazo esters

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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Certificates of Analysis (COA)

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A.J. Anciaux et al.
The Journal of Organic Chemistry, 45, 695-695 (1980)
A. De Meijere et al.
Synthesis, 547-547 (1991)

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