85325
Silver trifluoromethanesulfonate
≥98.0% (Ag), crystals, purum
Synonym(s):
Ag(OTf), Silver (trifluoromethyl)sulfonate, Silver triflate, Trifluoromethanesulfonic acid silver salt
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About This Item
Linear Formula:
CF3SO3Ag
CAS Number:
Molecular Weight:
256.94
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
220-882-2
MDL number:
Beilstein/REAXYS Number:
3598402
Product Name
Silver trifluoromethanesulfonate, purum, ≥98.0% (Ag)
grade
purum
Quality Level
assay
≥98.0% (Ag)
form
crystals
reaction suitability
core: silver, reagent type: catalyst
SMILES string
[Ag+].[O-]S(=O)(=O)C(F)(F)F
InChI
1S/CHF3O3S.Ag/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
InChI key
QRUBYZBWAOOHSV-UHFFFAOYSA-M
General description
Silver trifluoromethanesulfonate p-complexes of monoenes, dienes, trienes, monoynes and diynes have been prepared. It reacts with 2-fluoro- and 3-fluoro-4-alkoxystilbazoles to afford the mesomorphic complexes. Iodine monochloride/AgOTf constitutes an efficient promoter system for the O-glycoside synthesis.
Application
Silver trifluoromethanesulfonate (AgOTf) may be employed as a reagent during glucosylation of several alcohols. AgOTf in combination with p-nitrobenzenesulfenyl chloride may be employed as an activator for the glycosylation.
It may be used for the synthesis of the following:
It may be used for the synthesis of the following:
- cystine-containing peptides
- 3-aminoalkylated indoles
- benzo[b]oxepines and 2H-chromenes
- diversely substituted iminoimidazoazines
Other Notes
Reagent for the substitution of halides by triflate.; Reagent for the glycosylation of glycosyl halides; Reagent used for the deprotection of protected thiols
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signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Disulfide bond formation in S-acetamidomethyl cysteine-containing peptides by the combination of silver trifluoromethanesulfonate and dimethylsulfoxide/aqueous HCl.
Tamamura H, et al.
Tetrahedron Letters, 34(31), 4931-4934 (1993)
V. Pozsgay et al.
The Journal of Organic Chemistry, 46, 3761-3761 (1981)
P.J. Garegg et al.
Acta Chemica Scandinavica. Series B, 33, 116-116 (1979)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| TMT00136-1G | 04061825152592 |
| 85325-5G | 04061833024027 |
| 85325-25G | 04061833024003 |