86858
Tetrabutylammonium cyanoborohydride
purum, ≥98.0% (CHN)
Synonym(s):
Tetrabutylammonium cyanotrihydroborate
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About This Item
Linear Formula:
(CH3CH2CH2CH2)4N(BH3CN)
CAS Number:
Molecular Weight:
282.32
UNSPSC Code:
12352000
PubChem Substance ID:
EC Number:
256-073-6
MDL number:
InChI key
BOHYACMUNXBTGV-UHFFFAOYSA-N
InChI
1S/C16H36N.CH3BN/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1-3/h5-16H2,1-4H3;2H3/q+1;-1
SMILES string
[BH3-]C#N.CCCC[N+](CCCC)(CCCC)CCCC
grade
purum
assay
≥98.0% (CHN)
reaction suitability
reagent type: reductant
mp
144-146 °C (lit.), ~145 °C
Application
Reactant for:
- Hydroxymethylation reactions
- Radical carbonylation reactions
- Reduction reactions (reductant)
Other Notes
Selective, reductive displacement of alkyl halides and sulfonate esters; Review
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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R.O. Hutchins et al.
The Journal of Organic Chemistry, 42, 82-82 (1977)
R.O. Hutchins et al.
The Journal of Organic Chemistry, 46, 3571-3571 (1981)
R.O. Hutchins et al.
Organic preparations and procedures international, 11, 201-201 (1979)
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