86867
Tetrabutylammonium phosphate monobasic
purum, ≥97.0% (T)
Synonym(s):
Tetrabutylammonium dihydrogen phosphate
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About This Item
Linear Formula:
(CH3CH2CH2CH2)4N[OP(OH)2O]
CAS Number:
Molecular Weight:
339.45
EC Number:
226-947-1
UNSPSC Code:
12352116
PubChem Substance ID:
Beilstein/REAXYS Number:
5196532
MDL number:
InChI key
ARRNBPCNZJXHRJ-UHFFFAOYSA-M
InChI
1S/C16H36N.H3O4P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-5(2,3)4/h5-16H2,1-4H3;(H3,1,2,3,4)/q+1;/p-1
SMILES string
OP(O)([O-])=O.CCCC[N+](CCCC)(CCCC)CCCC
grade
purum
assay
≥97.0% (T)
form
solid
mp
151-154 °C (lit.)
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Other Notes
Mild acid; Preparation of allylic phosphates
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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A.I. Meyers et al.
Tetrahedron Letters, 26, 2047-2047 (1985)
M. Julia et al.
Tetrahedron, 42, 3841-3841 (1986)
Pieter van Dillewijn et al.
Applied and environmental microbiology, 74(21), 6820-6823 (2008-09-16)
Homogenous preparations of XenB of Pseudomonas putida, pentaerythritol tetranitrate reductase of Enterobacter cloacae, and N-ethylmaleimide reductase of Escherichia coli, all type II hydride transferases of the Old Yellow Enzyme family of flavoproteins, are shown to reduce the polynitroaromatic compound 2,4,6-trinitrotoluene
Fabio Galeotti et al.
Journal of chromatography. A, 1284, 141-147 (2013-03-05)
In this study, by using tetrabutylammonium bisulfate as ion-pairing reagent, we were able to separate all the main heparin/heparan sulfate disaccharides generated by the action of heparinases along with the main Hep tetrasaccharide possessing a 3-O-sulfate group on the sulfoglucosamine
Erbo Shi et al.
Organic letters, 14(13), 3384-3387 (2012-06-27)
A metal-free C-H oxidation for the construction of allylic esters has been developed. The use of a commercially available and inexpensive catalyst and oxidant, and readily available starting materials, coupled with the operational simplicity of the reaction, renders the methodology
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