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Merck
CN

86889

Tetrabutylammonium (meta)periodate

purum, moistened with water, ≥97.0% (calc. based on dry substance, T)

Synonym(s):

Tetrabutylammonium periodate

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About This Item

Linear Formula:
(CH3CH2CH2CH2)4N(IO4)
CAS Number:
Molecular Weight:
433.37
EC Number:
265-614-5
UNSPSC Code:
12352300
PubChem Substance ID:
Beilstein/REAXYS Number:
4621593
MDL number:
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grade

purum

assay

≥97.0% (calc. based on dry substance, T)

quality

moistened with water

contains

~10% water as stabilizer

reaction suitability

reagent type: oxidant

mp

175 °C (dec.) (lit.), 184-185 °C

SMILES string

[O-]I(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.HIO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1

InChI key

PYVXLMQALOZKES-UHFFFAOYSA-M

Other Notes

Versatile reagent for oxidation in organic solvents; Oxidation of 1,2-diols and olefins; Oxidation of sulfides to sulfoxides

pictograms

Flame over circleExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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T. Takata et al.
Tetrahedron Letters, 24, 3631-3631 (1983)
Synthesis, 568-568 (1980)
E. Santaniello et al.
Tetrahedron Letters, 21, 2655-2655 (1980)
K. Inomata et al.
Bulletin of the Chemical Society of Japan, 53, 565-565 (1980)

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