86900
Tetrabutylammonium fluoride solution
purum, ~1 M in THF
Synonym(s):
TBAF solution
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About This Item
Linear Formula:
[CH3(CH2)3]4NF
CAS Number:
Molecular Weight:
261.46
PubChem Substance ID:
UNSPSC Code:
12352116
Beilstein/REAXYS Number:
3762762
MDL number:
SMILES string
[F-].CCCC[N+](CCCC)(CCCC)CCCC
InChI
1S/C16H36N.FH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
InChI key
FPGGTKZVZWFYPV-UHFFFAOYSA-M
grade
purum
concentration
~1 M in THF
impurities
4-5% water
storage temp.
2-8°C
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Application
Reactant for preparation of:
- Triple monoamine reuptake inhibitors as a new generation of antidepressants
- Alcohols via hydrolysis of alkyl silyl ethers neutral pH in mixed organic-aqueous buffered solutions
- Oligoribonucleotides with phosphonate-modified linkages
- Aryl alkyl alcohols via Nozaki-Hiyama allylation catalyzed by chiral bipyridyldiol ligands and chromium trichloride
- Conjugated dienoic acid esters using Suzuki coupling reactions
- Macrocyclic o-aminobenzamide Hsp90 inhibitorwith antitumor activity
- Phospshoinositide 3-kinase (PI3K)/mammalian target of rapamycin (mTOR) dual inhibitors
- Anti-diabetic polyacetylenic glucosides
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
Regulatory Information
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Chao Zhong et al.
Carbohydrate polymers, 94(1), 38-45 (2013-04-03)
In this article, a novel and high efficient solvent, tetra-n-Butylammonium Hydroxide (TBAH), was used for dissolution and isolation of straw cellulose from wheat straw. The composition analysis with gas chromatography (GC) and the spectroscopic characterization analysis conducted by X-Ray diffraction
Noelia Luque et al.
Journal of chromatography. A, 1248, 74-83 (2012-06-26)
The suitability of a mixed-mode sorbent made up of admicelles of sodium dodecyl sulphate (SDS) and tetrabutylammonium (TBA) to extract and preserve pesticides from river and underground water was assessed. Pesticides belonging to different structural groups (i.e. triazines, carbamates, phenylureas
David J Posson et al.
Nature structural & molecular biology, 20(2), 159-166 (2012-12-25)
Understanding how ion channels open and close their pores is crucial for comprehending their physiological roles. We used intracellular quaternary ammonium blockers, electrophysiology and X-ray crystallography to locate the voltage-dependent gate in MthK potassium channels from Methanobacterium thermoautotrophicum. Blockers bind
Zhenfeng He et al.
Dalton transactions (Cambridge, England : 2003), 41(33), 10043-10051 (2012-05-29)
A new kind of organic-inorganic hybrid complexes based on polyoxometalate were synthesized through symmetrically grafting two adeninyl groups onto Anderson-type MnMo(6) clusters and encapsulating the clusters by organic surfactants. The resultant complexes exhibited thermal-induced dynamic self-assembly behaviors which greatly depended
Toshihiro Kimura et al.
Inorganic chemistry, 51(23), 13001-13008 (2012-11-15)
A simple monomeric tungstate, TBA(2)[WO(4)] (I, TBA = tetra-n-butylammonium), could act as an efficient homogeneous catalyst for chemical fixation of CO(2) with 2-aminobenzonitriles to quinazoline-2,4(1H,3H)-diones. Various kinds of structurally diverse 2-aminobenzonitriles could be converted into the corresponding quinazoline-2,4(1H,3H)-diones in high
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