87751
Diamide
≥99.0% (CHN)
Synonym(s):
1,1′-Azobis(N,N-dimethylformamide), N,N,N′,N′-Tetramethylazodicarboxamide, Azodicarboxylic acid bis(dimethylamide), Diazenedicarboxylic acid bis(N,N-dimethylamide), TMAD
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About This Item
Linear Formula:
(CH3)2NCON=NCON(CH3)2
CAS Number:
Molecular Weight:
172.19
EC Number:
233-951-7
UNSPSC Code:
12352202
PubChem Substance ID:
Beilstein/REAXYS Number:
1910409
MDL number:
InChI key
VLSDXINSOMDCBK-BQYQJAHWSA-N
InChI
1S/C6H12N4O2/c1-9(2)5(11)7-8-6(12)10(3)4/h1-4H3/b8-7+
SMILES string
CN(C)C(=O)\N=N\C(=O)N(C)C
assay
≥99.0% (CHN)
form
crystalline
color
yellow
storage temp.
−20°C
Other Notes
Reagent for Mitsunobu reactions of acids with high pK′s ; synthesis of cyclic ethers from diols
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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T. Tsunoda et al.
Chemistry Letters (Jpn), 539-539 (1994)
S. Harusawa et al.
Tetrahedron Letters, 37, 2463 -2463 (1996)
Yong Tao et al.
Insect biochemistry and molecular biology, 43(9), 820-828 (2013-06-29)
Anthranilic diamides, which include the new commercial insecticide, chlorantraniliprole, are an exciting new class of chemistry that target insect ryanodine receptors. These receptors regulate release of stored intracellular calcium and play a critical role in muscle contraction. As with insects
Mykhaylo A Potopnyk et al.
Organic letters, 14(16), 4258-4261 (2012-08-03)
A convenient route to macrocyclic diamide-linked macrocyclic derivatives with a sucrose scaffold is presented. Reaction of sucrose based amines (o- and m-) with acid dichlorides afforded the monomeric macrocycles in excellent yields, while reaction of the p-amines also provided dimeric
Mammalian cell studies with diamide.
J W Harris
Pharmacology & therapeutics, 7(2), 375-391 (1979-01-01)
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