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Merck
CN

87830

1,1,3,3-Tetramethyldisilazane

purum, ≥97.0% (GC)

Synonym(s):

TMDS

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About This Item

Linear Formula:
[(CH3)2SiH]2NH
CAS Number:
Molecular Weight:
133.34
EC Number:
240-072-2
UNSPSC Code:
12352103
MDL number:
Beilstein/REAXYS Number:
741869
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grade

purum

assay

≥97.0% (GC)

refractive index

n20/D 1.404 (lit.)

mp

99-100 °C

density

0.752 g/mL at 25 °C (lit.)

SMILES string

[H][Si](C)(C)N[Si]([H])(C)C

InChI

1S/C4H15NSi2/c1-6(2)5-7(3)4/h5-7H,1-4H3

InChI key

NQCZAYQXPJEPDS-UHFFFAOYSA-N

Other Notes

Silylating agent; Silylation/hydrosilylation of β-hydroxy alkenes to silolanes

Regulatory Information

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K. Blau et al.
Handbook of Derivatives for Chromatography (1993)
Stereocontrol in intramolecular hydrosilylation of allyl and homoallyl alcohols: a new approach to the stereoselective synthesis of 1,3-diol skeletons.
K Tamao et al.
Journal of the American Chemical Society, 108(19), 6090-6093 (1986-09-01)
M.R. Hale et al.
The Journal of Organic Chemistry, 57, 1643-1643 (1992)

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