88065
Tetraphenylphosphonium tetraphenylborate
Selectophore™
Synonym(s):
Tetraphenylboron tetraphenylphosphonium
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About This Item
Empirical Formula (Hill Notation):
C48H40BP
CAS Number:
Molecular Weight:
658.62
UNSPSC Code:
26111700
NACRES:
NB.61
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3890798
InChI
1S/C24H20B.C24H20P/c2*1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24/h2*1-20H/q-1;+1
SMILES string
c1ccc(cc1)[B-](c2ccccc2)(c3ccccc3)c4ccccc4.c5ccc(cc5)[P+](c6ccccc6)(c7ccccc7)c8ccccc8
InChI key
QYFWPOPFFBCTLK-UHFFFAOYSA-N
product line
Selectophore™
Quality Level
General description
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Other Notes
Lipophilic salt used in liquid-membrane anion-selective electrodes
Legal Information
Selectophore is a trademark of Merck KGaA, Darmstadt, Germany
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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H. Satake et al.
Analytical Letters, 24, 295-295 (1991)
Cunfa Sun et al.
ACS nano, 13(5), 5975-5986 (2019-05-09)
Copper-hydrides are known catalysts for several technologically important reactions such as hydrogenation of CO, hydroamination of alkenes and alkynes, and chemoselective hydrogenation of unsaturated ketones to unsaturated alcohols. Stabilizing copper-based particles by ligand chemistry to nanometer scale is an appealing
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