88126
Tetrapropylammonium perruthenate
purum
Synonym(s):
TPAP
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About This Item
Linear Formula:
(CH3CH2CH2)4NRuO4
CAS Number:
Molecular Weight:
351.43
MDL number:
UNSPSC Code:
12352000
PubChem Substance ID:
grade
purum
reaction suitability
reagent type: oxidant
mp
~160 °C (dec.) (lit.)
storage temp.
2-8°C
SMILES string
[O-][Ru](=O)(=O)=O.CCC[N+](CCC)(CCC)CCC
InChI
1S/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;
InChI key
NQSIKKSFBQCBSI-UHFFFAOYSA-N
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Other Notes
Catalyst for the mild N-methylmorpholine N-oxide, NMO, mediated oxidation of alcohols to carbonyl compounds in methylene chloride
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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S.V. Ley et al.
Synthesis, 639-639 (1994)
Alexandra Fidalgo et al.
Physical chemistry chemical physics : PCCP, 10(15), 2026-2032 (2008-08-09)
Fluorinated organo-silica gels doped with tetra-n-propylammonium perruthenate (TPAP) are excellent catalysts for the aerobic oxidative dehydrogenation of alcohols in supercritical CO2 (scCO2). Their activity and stability are subtly dictated by structure, depending on the degree of fluorination and on the
A double donor-activated ruthenium(VII) catalyst: synthesis of enantiomerically pure THF-diols.
Huan Cheng et al.
Angewandte Chemie (International ed. in English), 49(9), 1587-1590 (2010-02-04)
Brooks E Maki et al.
Organic letters, 11(7), 1651-1654 (2009-03-27)
Indoles and alcohols can be coupled in a dehydrogenative process catalyzed by tetrapropylammonium perruthenate. This efficient approach to indolylamides proceeds in a single flask under mild conditions. By employing substituted indoles and alkyl, branched, or benzylic alcohols, a variety of
C K Acosta et al.
Steroids, 58(5), 205-208 (1993-05-01)
Tetrapropylammonium perruthenate N-methylmorpholine N-oxide oxidation of steroidal alcohols is described. The reagent combination is mild and gave good yields of the corresponding ketones. Although the oxidation can generate ketones from 3-, 11-, 15-, 17-, and 20-hydroxy steroids, the oxidation of
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