88126
Tetrapropylammonium perruthenate
purum
Synonym(s):
TPAP
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About This Item
Linear Formula:
(CH3CH2CH2)4NRuO4
CAS Number:
Molecular Weight:
351.43
UNSPSC Code:
12352000
PubChem Substance ID:
MDL number:
grade
purum
reaction suitability
reagent type: oxidant
mp
~160 °C (dec.) (lit.)
storage temp.
2-8°C
SMILES string
[O-][Ru](=O)(=O)=O.CCC[N+](CCC)(CCC)CCC
InChI
1S/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;
InChI key
NQSIKKSFBQCBSI-UHFFFAOYSA-N
Other Notes
Catalyst for the mild N-methylmorpholine N-oxide, NMO, mediated oxidation of alcohols to carbonyl compounds in methylene chloride
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
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Brooks E Maki et al.
Organic letters, 11(7), 1651-1654 (2009-03-27)
Indoles and alcohols can be coupled in a dehydrogenative process catalyzed by tetrapropylammonium perruthenate. This efficient approach to indolylamides proceeds in a single flask under mild conditions. By employing substituted indoles and alkyl, branched, or benzylic alcohols, a variety of
Alexandra Fidalgo et al.
Physical chemistry chemical physics : PCCP, 10(15), 2026-2032 (2008-08-09)
Fluorinated organo-silica gels doped with tetra-n-propylammonium perruthenate (TPAP) are excellent catalysts for the aerobic oxidative dehydrogenation of alcohols in supercritical CO2 (scCO2). Their activity and stability are subtly dictated by structure, depending on the degree of fluorination and on the
S.V. Ley et al.
Synthesis, 639-639 (1994)