88885
Thiomorpholine
purum, ≥97.0% (GC)
Synonym(s):
Tetrahydro-2H-1,4-thiazine, Thiamorpholine
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About This Item
Empirical Formula (Hill Notation):
C4H9NS
CAS Number:
Molecular Weight:
103.19
EC Number:
204-660-2
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
102550
MDL number:
InChI key
BRNULMACUQOKMR-UHFFFAOYSA-N
InChI
1S/C4H9NS/c1-3-6-4-2-5-1/h5H,1-4H2
SMILES string
C1CSCCN1
grade
purum
assay
≥97.0% (GC)
refractive index
n20/D 1.538 (lit.), n20/D 1.540
bp
169 °C (lit.)
density
1.026 g/mL at 25 °C (lit.)
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
145.4 °F - closed cup
flash_point_c
63 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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J I Levin et al.
Bioorganic & medicinal chemistry letters, 16(6), 1605-1609 (2006-01-24)
A series of thiomorpholine sulfonamide hydroxamate TACE inhibitors, all bearing propargylic ether P1' groups, was explored. In particular, compound 5h has excellent in vitro potency against isolated TACE enzyme and in cells, oral activity in a model of TNF-alpha production
[Study of antiradiation drugs. I. Synthesis of some mercapto and amino derivatives of thiomorpholine (author's transl)].
F X Chen et al.
Yao xue xue bao = Acta pharmaceutica Sinica, 15(8), 482-488 (1980-08-01)
Dominik Cincić et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(2), 747-753 (2007-10-24)
We demonstrate the supramolecular and structural equivalence of two halogen-bond donors (I and Br) and three acceptors (O, NH and S) through the synthesis of seven isostructural halogen-bonded cocrystals, involving six different molecules: 1,4-dibromo- and 1,4-diiodotetrafluorobenzene (donors) and thiomorpholine, thioxane
Saurav Bera et al.
ACS combinatorial science, 14(1), 1-4 (2011-12-01)
Diastereoselective trans-2,5-disubstituted amino acids derived diverse morpholines, piperazines and thiomorpholines were prepared in 30 min-1 h with high yields through iodine-mediated 6-exotrig type cyclization from a single common synthetic intermediate. The displacement of iodine with hydride ion gave a methyl
B Combourieu et al.
Biodegradation, 9(6), 433-442 (1999-05-21)
Spectrophotometric assays of Mycobacterium aurum MO1 cells extracts gave evidence of a soluble cytochrome P450, involved in the degradative pathway of morpholine, a waste product from the chemical industry. In order to get further information, the kinetics of the biodegradation
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