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Merck
CN

89580

Supelco

o-Tolidine

for spectrophotometric det. of Au, Ce, Cl, free halogens, Mn, ≥98.0%

Synonym(s):

3,3′-Dimethylbenzidine, 4,4′-Bianisidine

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About This Item

Linear Formula:
[-C6H3(CH3)-4-NH2]2
CAS Number:
Molecular Weight:
212.29
Beilstein:
2210640
EC Number:
MDL number:
UNSPSC Code:
12161500
PubChem Substance ID:
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Assay

≥98.0% (NT)
≥98.0%

form

crystalline

quality

for spectrophotometric det. of Au, Ce, Cl, free halogens, Mn

technique(s)

titration: suitable

color

light brown

mp

128-131 °C (lit.)

solubility

2% HCl: 10 mg/mL, clear

SMILES string

Cc1cc(ccc1N)-c2ccc(N)c(C)c2

InChI

1S/C14H16N2/c1-9-7-11(3-5-13(9)15)12-4-6-14(16)10(2)8-12/h3-8H,15-16H2,1-2H3

InChI key

NUIURNJTPRWVAP-UHFFFAOYSA-N

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Application

Sensitive colorimetric reagent for gold and for free chlorine in water.

Analysis Note

Sensitivity:
1 mL of a 0.1% hydrochloric acid solution gives with 0.0025 mg active chlorine a visible yellow coloration.

Disclaimer

May be carcinogenic.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 1B

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

212.0 °F - closed cup

Flash Point(C)

100 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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S Torres-Cartas et al.
European journal of medicinal chemistry, 42(11-12), 1396-1402 (2007-05-08)
Mutagenicity is a toxicity endpoint associated with the chronic exposure to chemicals. Aromatic amines have considerable industrial and environmental importance due to their widespread use in industry and their mutagenic capacity. Biopartitioning micellar chromatography (BMC), a mode of micellar liquid

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