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Merck
CN

90120

p-Tolylhydrazine hydrochloride

purum, ≥98.0% (AT)

Synonym(s):

4-Methylphenylhydrazine hydrochloride

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About This Item

Linear Formula:
CH3C6H4NHNH2 · HCl
CAS Number:
637-60-5
Molecular Weight:
158.63
EC Number:
211-295-2
UNSPSC Code:
12352100
PubChem Substance ID:
329769851
Beilstein/REAXYS Number:
3563996
MDL number:
MFCD00012940

Key Documents

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InChI key

HMHWNJGOHUYVMD-UHFFFAOYSA-N

InChI

1S/C7H10N2.ClH/c1-6-2-4-7(9-8)5-3-6;/h2-5,9H,8H2,1H3;1H

SMILES string

Cl.Cc1ccc(NN)cc1

grade

purum

assay

≥98.0% (AT)

mp

>200 °C (dec.) (lit.)

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Skin Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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B Toth et al.
Journal of toxicology and environmental health, 8(1-2), 1-9 (1981-07-01)
4-Methylphenylhydrazine hydrochloride (4-MPH) was administered to randomly bred Swiss mice as 26 weekly sc injections of 140 microgram per gram of body weight and N'-acetyl-4-(hydroxymethyl)phenylhydrazine (AMPH) as 26 weekly sc injections of 500 microgram/g. As a solvent control, physiological saline
Qiang Tang et al.
Journal of the American Chemical Society, 130(18), 5840-5841 (2008-04-15)
An unexpected reaction of N,N-disubstituted hydrazine with naphthol and its analogues under simply thermal conditions has been disclosed. 2-Naphthol reacted with various N,N-disubstituted hydrazines under argon to afford 1-amino-2-naphthol and the corresponding secondary amines in excellent yields. Ortho amination of
Megumi Hamano Nagaokaa et al.
Chemical & pharmaceutical bulletin, 54(6), 922-924 (2006-06-07)
Agaricus blazei MURRILL mushroom products are sold as so-called health foods in Japan. However, a part of Agaricus is known to contain hydrazines. A sensitive and specific method for analyzing a genotoxic hydrazine, agaritine, and its derivatives was developed to

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