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Merck
CN

90550

Triethylsilane

purum, ≥97.0% (GC)

Synonym(s):

NSC 93579, Triethylhydrosilane, Triethylsilicon hydride

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About This Item

Linear Formula:
(C2H5)3SiH
CAS Number:
Molecular Weight:
116.28
EC Number:
210-535-3
UNSPSC Code:
12352000
MDL number:
Beilstein/REAXYS Number:
1098278
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grade

purum

assay

≥97.0% (GC)

reaction suitability

reagent type: reductant

refractive index

n20/D 1.412

bp

107-108 °C (lit.)

density

0.728 g/mL at 25 °C (lit.)

SMILES string

CC[SiH](CC)CC

InChI

1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3

InChI key

AQRLNPVMDITEJU-UHFFFAOYSA-N

Application

Catalyst for:
  • Synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain
  • Redox initiated cationic polymerization
  • Beckmann rearrangement of cyclododecanone oxime
  • Regioselective reductive coupling of enones and allenes

Catalyst reactivation after catalyst polymerization of styrene

Studies involving the prediction of organosilicon flash points

Other Notes

Reagent for the reduction of various functional groups (e.g. acyl halides to aldehydes, alkyl halides and secondary alcohols to hydrocarbons), review; Silylating agent for alcohols, phenols, etc.


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pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

21.2 °F

flash_point_c

-6 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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J. Heberle et al.
Silylating Agents, 2nd ed. (1995)
H. Yoda et al.
Tetrahedron Asymmetry, 4, 1451-1451 (1993)
Y. Nagai
Organic preparations and procedures international, 12, 13-13 (1980)