90570
Triethyl(trifluoromethyl)silane
purum, ≥98.0% (GC)
Synonym(s):
(Trifluoromethyl)triethylsilane, Triethylsilyl trifluoromethane
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About This Item
Linear Formula:
(C2H5)3SiCF3
CAS Number:
Molecular Weight:
184.27
PubChem Substance ID:
UNSPSC Code:
12352001
Beilstein/REAXYS Number:
4242161
MDL number:
SMILES string
CC[Si](CC)(CC)C(F)(F)F
InChI
1S/C7H15F3Si/c1-4-11(5-2,6-3)7(8,9)10/h4-6H2,1-3H3
InChI key
ZHSKFONQCREGOG-UHFFFAOYSA-N
grade
purum
assay
≥98.0% (GC)
reaction suitability
reaction type: C-C Bond Formation
bp
56-57 °C/60 mmHg (lit.)
density
0.98 g/mL at 25 °C (lit.)
Application
Reactant for:
- Trifluoromethylation of aryl iodides
- Trialkylsilylation reactions
- Used for deposition of perfluoro-methyl silica films
Other Notes
Reagent used for fluoride-induced nucleophilic trifluoromethylations. The higher boiling point of this comp. allows reactions at higher temperatures than with the tri-methyl analogue
Storage Class
12 - Non Combustible Liquids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Find documentation for the products that you have recently purchased in the Document Library.
H. Urata et al.
Tetrahedron Letters, 32, 91-91 (1991)
G.P. Stahly et al.
The Journal of Organic Chemistry, 54, 2873-2873 (1989)
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