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Merck
CN

90650

α-D-Ribofuranose 1,3,5-tribenzoate

purum, ≥97.0% (TLC)

Synonym(s):

1,3,5-Tri-O-benzoyl-α-D-ribofuranose

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About This Item

Empirical Formula (Hill Notation):
C26H22O8
CAS Number:
22224-41-5
Molecular Weight:
462.45
PubChem Substance ID:
24889390
UNSPSC Code:
12352200
Beilstein/REAXYS Number:
98446
MDL number:
MFCD00080818

Key Documents

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grade

purum

assay

≥97.0% (TLC)

optical activity

[α]20/D +86±2°, c = 1% in chloroform

mp

125-129 °C (lit.)

SMILES string

O=C(OC[C@H]1O[C@H](OC(=O)c2ccccc2)[C@H](OC(=O)c3ccccc3)[C@@H]1OC(=O)c4ccccc4)c5ccccc5

InChI

1S/C26H22O8/c27-21-22(33-24(29)18-12-6-2-7-13-18)20(16-31-23(28)17-10-4-1-5-11-17)32-26(21)34-25(30)19-14-8-3-9-15-19/h1-15,20-22,26-27H,16H2/t20-,21-,22-,26-/m1/s1

InChI key

HUHVPBKTTFVAQF-PIXQIBFHSA-N

Other Notes

Building block for preparing 2′-deoxy and 2′-O-substituted nucleosides

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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C. Lamberth
Organic preparations and procedures international, 26, 595-595 (1994)
A. Koch et al.
The Journal of Organic Chemistry, 58, 1083-1083 (1993)
Stereocontrolled de Novo Synthesis of beta-2'-Deoxyribonucleosides.
Minnie Park et al.
The Journal of organic chemistry, 61(18), 6092-6093 (1996-09-06)

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