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Merck
CN

91251

Supelco

1,2-Bis(2,4,6-tribromophenoxy)ethane

analytical standard

Synonym(s):

1,1′-[1,2-Ethanediylbis(oxy)]bis[2,4,6-tribromobenzene]

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About This Item

Empirical Formula (Hill Notation):
C14H8Br6O2
CAS Number:
37853-59-1
Molecular Weight:
687.64
Beilstein:
3168887
MDL number:
MFCD00071811
UNSPSC Code:
12352200
PubChem Substance ID:
329770015
NACRES:
NA.24

Key Documents

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grade

analytical standard

Quality Level

100

Assay

≥98.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

application(s)

environmental

format

neat

storage temp.

2-8°C

SMILES string

BrC1=C(OCCOC2=C(Br)C=C(Br)C=C2Br)C(Br)=CC(Br)=C1

InChI

1S/C14H8Br6O2/c15-7-3-9(17)13(10(18)4-7)21-1-2-22-14-11(19)5-8(16)6-12(14)20/h3-6H,1-2H2

InChI key

YATIGPZCMOYEGE-UHFFFAOYSA-N

General description

1,2-Bis(2,4,6-tribromophenoxy)ethanes (BTBPEs) are a type of brominated flame retardants (BFRs), which are widely used in domestic and commercial products to prevent fire propagation.

Application

BTBPE may be used as a reference standard for the determination of the analyte in soils, in foods, in air and biota samples and in human hair and nails by gas chromatography-mass spectrometry (GC-MS).

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H315,H318,H335

Hazard Classifications

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
BCBZ9731
BCBR6643V
BCBR6643

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Simultaneous determination of three alternative flame retardants (dechlorane plus, 1, 2-bis (2, 4, 6-tribromophenoxy) ethane, and decabromodiphenyl ethane) in soils by gas chromatography-high resolution mass spectrometry
Xu P, et al.
Talanta, 144, 1014-1020 (2015)
Novel brominated flame retardants and dechlorane plus in Greenland air and biota
Vorkamp K, et al.
Environmental Pollution (Barking, Essex : 1987), 196, 284-291 (2015)
Maeva Giraudo et al.
Aquatic toxicology (Amsterdam, Netherlands), 186, 40-49 (2017-03-02)
Brominated flame retardants (BFRs) represent a large group of chemicals used in a variety of household and commercial products to prevent fire propagation. The environmental persistence and toxicity of some of the most widely used BFRs has resulted in a
Atmospheric Pressure Chemical Ionization Gas Chromatography Mass Spectrometry for the Analysis of Selected Emerging Brominated Flame Retardants in Foods
Lv S, et al.
Scientific reports, 7, 43998-43998 (2017)
Huiying Guo et al.
Journal of hazardous materials, 393, 122397-122397 (2020-03-03)
Leaching kinetics of additive-derived brominated flame retardants (BFRs) in different sizes (100 μm-2 mm) of acrylonitrile-butadiene-styrene copolymer (ABS) plastics were investigated in water, simulated gastric fluids, and simulated gastrointestinal fluids. The influences of bird diets (fish, clam, and rice) on the leaching
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