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Merck
CN

916250

[(IMes)AuCl]

Umicore, powder

Synonym(s):

Chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]gold(I), 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene gold(I) chloride

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About This Item

Empirical Formula (Hill Notation):
C21H24AuClN2
CAS Number:
852445-81-9
Molecular Weight:
536.85
NACRES:
NA.22
UNSPSC Code:
12352005
MDL number:
MFCD11656059

Key Documents

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Product Name

[(IMes)AuCl], Umicore

InChI

1S/C21H24N2.Au.ClH/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;;/h7-12H,1-6H3;;1H/q;+1;/p-1

SMILES string

Cl[Au].Cc1cc(C)c(N2[C]N(C=C2)c3c(C)cc(C)cc3C)c(C)c1

InChI key

YFUIKJIITPMUAT-UHFFFAOYSA-M

form

powder

mp

>300 °C, >300 °C

Quality Level

100

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Application

[(IMes)AuCl] is a homogeneous catalyst useful for cyclopropanation or carboxylation.

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

Preparation Note

Do not store above 25°C (77°F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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