92766
(Trimethylsilyl)methanol
purum, ≥97.0% (GC)
Synonym(s):
(Hydroxymethyl)trimethylsilane
Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
About This Item
Linear Formula:
(CH3)3SiCH2OH
CAS Number:
Molecular Weight:
104.22
EC Number:
221-746-5
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1731486
MDL number:
grade
purum
assay
≥97.0% (GC)
refractive index
n20/D 1.419
bp
120-122 °C/754 mmHg (lit.)
density
0.826 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
C[Si](C)(C)CO
InChI
1S/C4H12OSi/c1-6(2,3)4-5/h5H,4H2,1-3H3
InChI key
ZQKNBDOVPOZPLY-UHFFFAOYSA-N
Other Notes
Starting material for the synthesis of trimethylsilylmethyl triflate; nucleophilic hydroxymethylation with the corresponding lithium carbonate; oxidation to the aldehyde and addition reactions
Regulatory Information
新产品
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
K. Baum et al.
The Journal of Organic Chemistry, 43, 203-203 (1978)
R.J. Linderman et al.
The Journal of Organic Chemistry, 53, 1569-1569 (1988)
S W Tsai et al.
Enzyme and microbial technology, 16(4), 328-333 (1994-04-01)
Enantioselective esterification of naproxen, 2-(6-methoxy-2-naphthyl) propionic acid, was attempted by lipases in nearly anhydrous isooctane. The nature of the alcohol affects the reactivity and enantioselectivity of the lipase from Candida cylindracea. Alcohols containing a trimethylsilyl group are highly reactive and