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Merck
CN

92785

2-(Trimethylsilyl)thiazole

purum, ≥97.0% (GC)

Synonym(s):

2-TST, 2-Thiazolyltrimethylsilane

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About This Item

Empirical Formula (Hill Notation):
C6H11NSSi
CAS Number:
Molecular Weight:
157.31
PubChem Substance ID:
UNSPSC Code:
12352100
Beilstein/REAXYS Number:
3538017
MDL number:
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SMILES string

C[Si](C)(C)c1nccs1

InChI

1S/C6H11NSSi/c1-9(2,3)6-7-4-5-8-6/h4-5H,1-3H3

InChI key

VJCHUDDPWPQOLH-UHFFFAOYSA-N

grade

purum

assay

≥97.0% (GC)

refractive index

n20/D 1.497 (lit.), n20/D 1.498

bp

56-57 °C/10 mmHg (lit.)

density

0.985 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Other Notes

Starting material for the synthesis of 2-acylthiazoles; Formyl anion equivalent in the diastereoselective addition to aldehydes

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

143.6 °F - closed cup

flash_point_c

62 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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A. Dondoni et al.
Organic Syntheses, 72, 21-21 (1995)
A. Dondoni et al.
The Journal of Organic Chemistry, 58, 3196-3196 (1993)

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