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Merck
CN

92828

Trioctylamine

puriss., ≥99.0% (NT)

Synonym(s):

TOA

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About This Item

Linear Formula:
[CH3(CH2)7]3N
CAS Number:
1116-76-3
Molecular Weight:
353.67
EC Number:
214-242-1
UNSPSC Code:
12352100
PubChem Substance ID:
24889735
Beilstein/REAXYS Number:
1210618
MDL number:
MFCD00009560

Key Documents

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grade

puriss.

assay

≥99.0% (NT)

refractive index

n20/D 1.449 (lit.), n20/D 1.450

bp

164-168 °C/0.7 mmHg (lit.), 365-367 °C (lit.)

solubility

chloroform: 0.1 g/mL, clear, colorless

density

0.810 g/mL at 20 °C, 0.809 g/mL at 25 °C (lit.)

SMILES string

CCCCCCCCN(CCCCCCCC)CCCCCCCC

InChI

1S/C24H51N/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

InChI key

XTAZYLNFDRKIHJ-UHFFFAOYSA-N

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Danger

Hazard Classifications

Aquatic Chronic 2 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1 Oral

target_organs

Heart

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

334.4 °F - closed cup

flash_point_c

168 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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M L Puttemans et al.
Journal - Association of Official Analytical Chemists, 66(4), 1039-1044 (1983-07-01)
Dyes are determined in gelatin-containing sweets. The gelatin must be eliminated first because it interferes with the normal ion-pair extraction of dyes with tri-n-octylamine to chloroform. Techniques such as precipitation of gelatin with organic solvents, and acid and enzymatic digestion
C N Lin et al.
Biotechnology and bioengineering, 69(1), 31-38 (2000-05-23)
A lipase-catalyzed enantioselective hydrolysis process under conditions of continuous in situ racemization of substrate with trioctylamine as the catalyst was developed for the production of (S)-suprofen from (R,S)-suprofen 2,2,2-trifluoroethyl thioester in isooctane. A detailed investigation of trioctylamine concentration on the
L W Wang et al.
Bioprocess and biosystems engineering, 27(1), 39-49 (2005-01-13)
A Candida rugosa lipase immobilized on polypropylene powder was employed as the biocatalyst for the enantioselective hydrolysis of (R, S)-suprofen 2,2,2-trifluorothioester in cyclohexane, in which trioctylamine was added as the catalyst to perform in situ racemization of the remaining (R)-thioester.
Enyi Ye et al.
Physical chemistry chemical physics : PCCP, 12(38), 11923-11929 (2010-09-08)
In this paper, weak acids, weak bases or their mixtures were used as reaction media/coordinating ligands to achieve systematic morphological control over amphoteric indium oxide nanostructures. Different indium/oleic acid molar ratios from 1 : 0, 1 : 1, 1 : 2, 1 : 3, 1 : 6 and 1 : 15 in
Young-Si Jun et al.
Biotechnology progress, 21(6), 1673-1679 (2005-12-03)
Kinetic studies for the extraction of succinic acid from aqueous solution with 1-octanol solutions of tri-n-octylamine (TOA) were carried out using a stirred cell with a microporous hydrophobic membrane. The interfacial concentrations of species were correlated and thus the intrinsic
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