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Merck
CN

93130

Triphenylsilane

purum, ≥97.0% (GC)

Synonym(s):

1,1′,1′′-Silylidynetrisbenzene, NSC 12565, Triphenylhydrosilane

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About This Item

Linear Formula:
(C6H5)3SiH
CAS Number:
Molecular Weight:
260.41
EC Number:
212-333-0
UNSPSC Code:
12352000
PubChem Substance ID:
Beilstein/REAXYS Number:
978182
MDL number:
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grade

purum

assay

≥97.0% (GC)

reaction suitability

reagent type: reductant

bp

152 °C/2 mmHg (lit.)

mp

43-45 °C

SMILES string

c1ccc(cc1)[SiH](c2ccccc2)c3ccccc3

InChI

1S/C18H16Si/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H

InChI key

AKQNYQDSIDKVJZ-UHFFFAOYSA-N

Application

Reactant or reagent:
  • For catalytic hydrogen deuterium exchange reactions of silanes
  • To be oxidized by carbon nanotube-gold nanohybrids
  • For hydrolysis by ruthenium complexes
  • For hydrosilylation to produce enolsilanes
  • For synthesis of bromosilanes
  • For ozone oxidation of silyl-alkenes for synthesis of α-O-silylated acyloin derivatives
  • Used to synthesize hydrido silyl and bis(silyl) bis(imidazolinylidene) nickel complexes

Other Notes

Silylating agent


Regulatory Information

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L. Horner et al.
Journal of Organometallic Chemistry, 282, 155-155 (1985)