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93132

Triphenylsilanethiol

Name: Triphenylsilanethiol
Brand: SIAL

purum, ≥97.0% (GC)

Synonym(s):

Mercaptotriphenylsilane

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About This Item

Linear Formula:

(C₆H₅)₃SiSH

CAS Number:

14606-42-9

Molecular Weight:

292.47

MDL number:

MFCD00192551

PubChem Substance ID:

24889804

UNSPSC Code:

12352103

Beilstein/REAXYS Number:

2941369

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grade

purum

assay

≥97.0% (GC)

mp

101-104 °C

SMILES string

S[Si](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C18H16SSi/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H

InChI key

MQDRKELSDPESDZ-UHFFFAOYSA-N

Other Notes

Solid equivalent of H₂S. Opening of epoxides to β-hydroxy thiols; Free-radical addition to olefins to give thiols

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J. Brittain et al.

Tetrahedron Letters, 34, 3363-3363 (1993)

B. Hache et al.

Tetrahedron Letters, 35, 1837-1837 (1994)

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