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Merck
CN

93387

Europium(III) tris[3-(trifluoromethylhydroxymethylene)-d-camphorate]

purum, ≥95.0% (CH)

Synonym(s):

Eu(facam)3, Eu(tfc)3, Tris(3-trifluoroacetyl-d-camphorato)europium(III), Tris[3-(trifluoromethylhydroxymethylene)-d-camphorato]europium(III)

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About This Item

Empirical Formula (Hill Notation):
C36H42EuF9O6
CAS Number:
Molecular Weight:
893.66
PubChem Substance ID:
UNSPSC Code:
12352000
EC Number:
252-232-9
MDL number:
Beilstein/REAXYS Number:
7509819
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SMILES string

CC1(C)C2CCC1(C)C(=O)\C2=C(/O[Eu](O\C(=C3\C4CCC(C)(C3=O)C4(C)C)C(F)(F)F)O\C(=C5\C6CCC(C)(C5=O)C6(C)C)C(F)(F)F)C(F)(F)F

grade

purum

assay

≥95.0% (CH)

mp

~200 °C (dec.)

Other Notes

Chiral shift reagent for the determination of enantiomer ratios by NMR

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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H.L. Goering et al.
Journal of the American Chemical Society, 93, 5913-5913 (1971)
H.J.C. Yeh et al.
The Journal of Organic Chemistry, 51, 5439-5439 (1986)
G.R. Sulivan
Topics in Stereochemistry, 10, 287-287 (1978)
L.M. Sweeting et al.
The Journal of Organic Chemistry, 52, 2273-2273 (1987)
R.R. Fraser et al.
Asymmetric Synthesis, 1, 173-173 (1983)

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