93414
Tri(p-tolyl)phosphine
purum, ≥97.0% (GC)
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About This Item
Linear Formula:
(CH3C6H4)3P
CAS Number:
Molecular Weight:
304.37
EC Number:
213-863-5
UNSPSC Code:
12350000
MDL number:
Beilstein/REAXYS Number:
651045
grade
purum
assay
≥97.0% (GC)
mp
144-148 °C
SMILES string
Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc(C)cc3
InChI
1S/C21H21P/c1-16-4-10-19(11-5-16)22(20-12-6-17(2)7-13-20)21-14-8-18(3)9-15-21/h4-15H,1-3H3
InChI key
WXAZIUYTQHYBFW-UHFFFAOYSA-N
Other Notes
Ligand used in organometallic chemistry
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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L.H. Pignolet
Homogeneous Catalysis with Metal Phosphine Complexes (1983)
E.C. Alyea et al.
Catalytic Aspects of Metal Phosphine Complexes (1982)
C.A. McAuliffe et al.
Phosphine, Arsine and Stibine Complexesof the Transition Elem. (1979)
Katherine A Parrish et al.
Physical chemistry chemical physics : PCCP, 21(4), 1689-1699 (2018-09-28)
This study examined the solution-phase exchange reactions of triphenylphosphine (PPh3) ligands on Au8L72+ (L = PPh3) gold clusters with three different tolyl ligands using electrospray ionization mass spectrometry to provide insight into how steric differences in the phosphines influence the
C.A. Tolman
Chemical Reviews, 77, 313-313 (1977)
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