95100
Trimethyl(vinyl)silane
purum, ≥97.0% (GC)
Synonym(s):
(Trimethylsilyl)ethylene, Ethenyltrimethylsilane
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About This Item
Linear Formula:
(CH3)3SiCHCH2
CAS Number:
Molecular Weight:
100.23
EC Number:
212-042-9
UNSPSC Code:
12352103
PubChem Substance ID:
Beilstein/REAXYS Number:
956572
MDL number:
InChI key
GCSJLQSCSDMKTP-UHFFFAOYSA-N
InChI
1S/C5H12Si/c1-5-6(2,3)4/h5H,1H2,2-4H3
SMILES string
C[Si](C)(C)C=C
vapor pressure
4.44 psi ( 20 °C)
grade
purum
assay
≥97.0% (GC)
bp
55 °C (lit.)
density
0.684 g/mL at 25 °C (lit.)
Other Notes
Review
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-11.2 °F
flash_point_c
-24 °C
ppe
Eyeshields, Faceshields, Gloves
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E.W. Colvin
Silicon Reagents for Organic Synthesis (1988)
Szlavik et al.
Organic letters, 2(15), 2347-2349 (2000-08-10)
A convenient and effective method for the preparation of perfluoroalkylated ethenes is described. First, the free radical addition of perfluoroalkyl iodides to trimethylvinylsilane in the presence of AIBN gave iodoethylsilane intermediates (F(CF(2))(n)()CH(2)CHISiMe(3), n = 4 (1), 6 (2), 8 (3)
K. Oshima
Sci. Synth., 4, 713-713 (2002)
E.W. Colvin
Chemical Society Reviews, 7, 15-15 (1978)
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