95100
Trimethyl(vinyl)silane
purum, ≥97.0% (GC)
Synonym(s):
(Trimethylsilyl)ethylene, Ethenyltrimethylsilane
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About This Item
Linear Formula:
(CH3)3SiCHCH2
CAS Number:
Molecular Weight:
100.23
Beilstein:
956572
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
vapor pressure
4.44 psi ( 20 °C)
grade
purum
Assay
≥97.0% (GC)
refractive index
n20/D 1.391 (lit.)
n20/D 1.391
bp
55 °C (lit.)
density
0.684 g/mL at 25 °C (lit.)
SMILES string
C[Si](C)(C)C=C
InChI
1S/C5H12Si/c1-5-6(2,3)4/h5H,1H2,2-4H3
InChI key
GCSJLQSCSDMKTP-UHFFFAOYSA-N
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Other Notes
Review
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
-11.2 °F
Flash Point(C)
-24 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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E.W. Colvin
Silicon Reagents for Organic Synthesis (1988)
Szlavik et al.
Organic letters, 2(15), 2347-2349 (2000-08-10)
A convenient and effective method for the preparation of perfluoroalkylated ethenes is described. First, the free radical addition of perfluoroalkyl iodides to trimethylvinylsilane in the presence of AIBN gave iodoethylsilane intermediates (F(CF(2))(n)()CH(2)CHISiMe(3), n = 4 (1), 6 (2), 8 (3)
K. Oshima
Sci. Synth., 4, 713-713 (2002)
E.W. Colvin
Chemical Society Reviews, 7, 15-15 (1978)
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