95463
Deoxo-Fluor
purum, ≥97.0% (NMR)
Synonym(s):
Bis(2-methoxyethyl)aminosulfur trifluoride
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About This Item
Linear Formula:
(CH3OCH2CH2)2NSF3
CAS Number:
Molecular Weight:
221.24
UNSPSC Code:
12352101
MDL number:
grade
purum
assay
≥97.0% (NMR)
density
1.2 g/mL at 25 °C (lit.)
SMILES string
COCCN(CCOC)S(F)(F)F
InChI
1S/C6H14F3NO2S/c1-11-5-3-10(4-6-12-2)13(7,8)9/h3-6H2,1-2H3
InChI key
APOYTRAZFJURPB-UHFFFAOYSA-N
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R.P. Singh, J.M. Shreeve
Journal of Fluorine Chemistry, 116, 23-23 (2002)
Lal et al.
The Journal of organic chemistry, 65(16), 4830-4832 (2000-08-24)
A variety of thiocarbonyl derivatives (thioketone, thioester, thioamide, dithioester, and dithiocarbamate) were converted to the corresponding gem-difluorides in excellent yields on reaction with the fluorinating agent, bis(2-methoxyethyl)aminosulfur trifluoride, in the presence of SbCl(3).
Fluorinating agent with high thermal stability.
S. Lal-Gauri et al.
The Journal of Organic Chemistry, 64, 7048-7048 (1999)
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