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Merck
CN

96480

Sigma-Aldrich

Zinc dimethyldithiocarbamate

purum, ≥97.0% (KT)

Synonym(s):

Dimethyldithiocarbamic acid zinc salt, Ziram

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About This Item

Linear Formula:
(CH3)2NCSSZnSCSN(CH3)2
CAS Number:
Molecular Weight:
305.82
Beilstein:
3707008
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
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grade

purum

Assay

≥97.0% (KT)

reaction suitability

reagent type: catalyst
core: zinc

mp

248-257 °C (lit.)
248-257 °C

SMILES string

CN(C)C(=S)S[Zn]SC(=S)N(C)C

InChI

1S/2C3H7NS2.Zn/c2*1-4(2)3(5)6;/h2*1-2H3,(H,5,6);/q;;+2/p-2

InChI key

DUBNHZYBDBBJHD-UHFFFAOYSA-L

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Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3

Target Organs

Liver,Blood, Respiratory system

Storage Class Code

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

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Zisis Vryzas et al.
Journal of agricultural and food chemistry, 50(8), 2220-2226 (2002-04-04)
A simple and rapid method is presented for the analysis of residues of ethylenebis(dithiocarbamate) (maneb, zineb, and mancozeb) and N,N-dimethyldithiocarbamate (thiram and ziram) fungicides in dry tobacco leaves and peaches. Residues are extracted and hydrolyzed to CS(2) in a single
Q Li et al.
International journal of immunopathology and pharmacology, 25(4), 883-891 (2013-01-10)
We previously found that ziram, a dithiocarbamate fungicide, significantly inhibited natural killer (NK) activity in a dose-dependent manner. To explore the mechanism of this inhibition, we investigated ziram-induced apoptosis in human NK cells. Human NK-92MI cells were treated with ziram
Wim H De Jong et al.
Toxicology, 176(1-2), 123-134 (2002-06-14)
A modified local lymph node assay (LLNA) was used to determine the sensitising activity of four chemicals used for the production of natural rubber latex products. Tetramethylthiuramdisulfide (TMTD), 2-mercaptobenzothiazole (MBT) and zincdimethyldithiocarbamate (ZDMC), three moderate human sensitisers, and diethylamine (DEA)
Ashok Kumar Malik et al.
Journal of AOAC International, 85(1), 146-148 (2002-03-09)
A method was developed for the determination of zinc(II) dimethyldithiocarbamate by converting it into the copper(II) dithiocarbamate complex, which is then extracted into molten naphthalene. The absorbance is measured at 430 nm versus a reagent blank. Beer's law is obeyed
Patch testing with zinc dibenzyldithiocarbamate. A multicentre study of the Information Network of Departments of Dermatology and the German Contact Dermatitis Research Group.
Johannes Geier et al.
Contact dermatitis, 48(4), 209-211 (2003-06-06)

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