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Merck
CN

96480

Zinc dimethyldithiocarbamate

purum, ≥97.0% (KT)

Synonym(s):

Dimethyldithiocarbamic acid zinc salt, Ziram

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About This Item

Linear Formula:
(CH3)2NCSSZnSCSN(CH3)2
CAS Number:
137-30-4
Molecular Weight:
305.82
EC Number:
205-288-3
UNSPSC Code:
12352300
PubChem Substance ID:
329770513
Beilstein/REAXYS Number:
3707008
MDL number:
MFCD00064797

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InChI key

DUBNHZYBDBBJHD-UHFFFAOYSA-L

InChI

1S/2C3H7NS2.Zn/c2*1-4(2)3(5)6;/h2*1-2H3,(H,5,6);/q;;+2/p-2

SMILES string

CN(C)C(=S)S[Zn]SC(=S)N(C)C

grade

purum

assay

≥97.0% (KT)

reaction suitability

reagent type: catalyst
core: zinc

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3

target_organs

Liver,Blood, Respiratory system

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Wim H De Jong et al.
Toxicology, 176(1-2), 123-134 (2002-06-14)
A modified local lymph node assay (LLNA) was used to determine the sensitising activity of four chemicals used for the production of natural rubber latex products. Tetramethylthiuramdisulfide (TMTD), 2-mercaptobenzothiazole (MBT) and zincdimethyldithiocarbamate (ZDMC), three moderate human sensitisers, and diethylamine (DEA)
Zisis Vryzas et al.
Journal of agricultural and food chemistry, 50(8), 2220-2226 (2002-04-04)
A simple and rapid method is presented for the analysis of residues of ethylenebis(dithiocarbamate) (maneb, zineb, and mancozeb) and N,N-dimethyldithiocarbamate (thiram and ziram) fungicides in dry tobacco leaves and peaches. Residues are extracted and hydrolyzed to CS(2) in a single
Q Li et al.
International journal of immunopathology and pharmacology, 25(4), 883-891 (2013-01-10)
We previously found that ziram, a dithiocarbamate fungicide, significantly inhibited natural killer (NK) activity in a dose-dependent manner. To explore the mechanism of this inhibition, we investigated ziram-induced apoptosis in human NK cells. Human NK-92MI cells were treated with ziram
Patch testing with zinc dibenzyldithiocarbamate. A multicentre study of the Information Network of Departments of Dermatology and the German Contact Dermatitis Research Group.
Johannes Geier et al.
Contact dermatitis, 48(4), 209-211 (2003-06-06)
Ashok Kumar Malik et al.
Journal of AOAC International, 85(1), 146-148 (2002-03-09)
A method was developed for the determination of zinc(II) dimethyldithiocarbamate by converting it into the copper(II) dithiocarbamate complex, which is then extracted into molten naphthalene. The absorbance is measured at 430 nm versus a reagent blank. Beer's law is obeyed
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