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Merck
CN

96915

Sigma-Aldrich

Z-Met-OMe

≥99.0% (sum of enantiomers, HPLC)

Synonym(s):

Z-L-methionine methyl ester

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About This Item

Linear Formula:
C6H5CH2OOCNHCH(COOCH3)CH2CH2SCH3
CAS Number:
56762-93-7
Molecular Weight:
297.37
Beilstein:
2144306
MDL number:
MFCD00145551
UNSPSC Code:
12352200
PubChem Substance ID:
329770537

Key Documents

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Assay

≥99.0% (sum of enantiomers, HPLC)

optical activity

[α]20/D −34±2°, c = 1% in methanol

mp

41-44 °C

application(s)

peptide synthesis

SMILES string

COC(=O)[C@H](CCSC)NC(=O)OCc1ccccc1

InChI

1S/C14H19NO4S/c1-18-13(16)12(8-9-20-2)15-14(17)19-10-11-6-4-3-5-7-11/h3-7,12H,8-10H2,1-2H3,(H,15,17)/t12-/m0/s1

InChI key

YGDBSBBHEWHVAJ-LBPRGKRZSA-N

Other Notes

Intermediate for the synthesis of derivatives of L-vinylglycine [(S)-2-amino-3-butenoic acid]

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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A. Afzali-Arkadani et al.
The Journal of Organic Chemistry, 45, 4817-4817 (1980)
P. Meffre et al.
Synthetic Communications, 19, 3457-3457 (1989)
Synthesis of 2'-epi-distichonic acid A, an iron-chelating amino acid derivative.
T Tashiro et al.
Chemical & pharmaceutical bulletin, 36(3), 893-901 (1988-03-01)

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