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Merck
CN

A7972

9-Anthryldiazomethane

Synonym(s):

9-(Diazomethyl)anthracene, ADAM

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About This Item

Empirical Formula (Hill Notation):
C15H10N2
CAS Number:
Molecular Weight:
218.25
UNSPSC Code:
12171500
MDL number:
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SMILES string

[N-]=[N+]=Cc1c2ccccc2cc3ccccc13

shipped in

dry ice

storage temp.

−20°C

Application

Common fluorescent diazomethane analogue used to derivatize biomolecules. Also has been used to detect several types of acids, including amino acids, bile acids, fatty acids, prostaglandins, and steroid acids.

pictograms

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Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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A Jakobsson et al.
Biochimica et biophysica acta, 1046(3), 277-287 (1990-10-01)
Isolated hepatocytes were incubated in the presence of [14C]palmitic, [14C]linoleic or [14C]linolenic acid and the time-courses of incorporation of radioactivity into phosphatidylcholine and phosphatidylethanolamine of microsomes and mitochondria were followed. For this purpose a procedure was developed for HPLC separation
P Demin et al.
Analytical biochemistry, 226(2), 252-255 (1995-04-10)
Facile methods for the detection of intact hepoxilins, monohydroxy-epoxide derivatives of arachidonic acid formed through the 12-lipoxygenase pathway, are unavailable because (i) an absence in these compounds of an appropriate chromophore for sensitive detection by uv exists, (ii) these compounds
E Alexandridis et al.
Alimentary pharmacology & therapeutics, 40(5), 467-476 (2014-07-22)
Transnasal endoscopy (TNE) with ultrathin endoscopes has been advocated as an attractive alternative, for diagnostic upper endoscopy. To assess tolerability, acceptability and quality of TNE, in comparison with standard upper endoscopy (SOGD, standard oesophago-gastro-duodenoscopy) under local anaesthetic. We prospectively recruited
Micha A Haeuptle et al.
Analytical biochemistry, 396(1), 133-138 (2009-09-19)
Dolichols (Dol) are polyprenol lipids that are essential structural components of eukaryotic membranes. In addition, the phosphorylated derivatives of Dol function as lipid anchors of mono- and oligosaccharide precursors involved in protein glycosylation. The biological importance of Dol phosphates (Dol-P)
M A Quilliam
Journal of AOAC International, 78(2), 555-570 (1995-03-01)
Diarrhetic shellfish poisoning (DSP) is a severe gastrointestinal illness caused by consumption of shellfish contaminated with toxigenic dinoflagellates. The main toxins responsible for DSP are okadaic acid (OA), DTX-1, DTX-2, and DTX-3, the latter being a complex mixture of 7-O-acyl

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