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Merck
CN

A7972

Sigma-Aldrich

9-Anthryldiazomethane

Synonym(s):

9-(Diazomethyl)anthracene, ADAM

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About This Item

Empirical Formula (Hill Notation):
C15H10N2
CAS Number:
Molecular Weight:
218.25
MDL number:
UNSPSC Code:
12171500
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shipped in

dry ice

storage temp.

−20°C

SMILES string

[N-]=[N+]=Cc1c2ccccc2cc3ccccc13

Application

Common fluorescent diazomethane analogue used to derivatize biomolecules. Also has been used to detect several types of acids, including amino acids, bile acids, fatty acids, prostaglandins, and steroid acids.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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P Demin et al.
Journal of chromatography. B, Biomedical applications, 672(2), 282-289 (1995-10-20)
Fluorescent anthryl (ADAM) derivatives of hepoxilins have been shown to possess good chromatographic properties affording good sensitivity for the high-performance liquid chromatographic analysis and detection of these compounds and related eicosanoids (12-hydroxyeicosatetraenoic acid) in biological samples. We report herein the
R Draisci et al.
Journal of chromatography. A, 798(1-2), 137-145 (1998-05-02)
A new analogue of okadaic acid (OA), the toxin mainly responsible for diarrhetic shellfish-poisoning (DSP) phenomena in Europe, has been isolated from toxic phytoplankton (Dinophysis acuta) collected in Irish waters. Fluorimetric LC analyses of the extracts of bulk phytoplankton samples
T H Roemen et al.
Journal of chromatography, 570(2), 243-251 (1991-10-04)
A high-performance liquid chromatographic technique for the rapid assessment fatty acids in cardiac tissue is described. A level of 50.4 +/- 14.9 nmol fatty acids per g wet weight of rat myocardial tissue could be monitored. The content of the
O B Stabell et al.
Toxicon : official journal of the International Society on Toxinology, 29(1), 21-29 (1991-01-01)
Okadaic acid and dinophysistoxin-1, the principal toxic components in diarrhetic shellfish poisoning, may be detected by high-performance liquid chromatography and fluorometric measurement as 9-anthrylmethyl esters. However, "greasy" samples may occur and the fluorescent reagent 9-anthryldiazomethane may decompose during storage, resulting
Sheng-Feng Lai et al.
Journal of nanobiotechnology, 13, 85-85 (2015-11-22)
Nanoparticles can be used for targeted drug delivery, in particular for brain cancer therapy. However, this requires a detailed analysis of nanoparticles from the associated microvasculature to the tumor, not easy because of the required high spatial resolution. The objective

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