B2633
tert-Butyl hydroperoxide solution
70% in H2O
Synonym(s):
1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane, TBHP
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About This Item
Linear Formula:
(CH3)3COOH
CAS Number:
Molecular Weight:
90.12
UNSPSC Code:
12162002
Beilstein/REAXYS Number:
1098280
MDL number:
reaction suitability
reagent type: oxidant
concentration
70% in H2O
density
0.94 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
CC(C)(C)OO
InChI
1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3
InChI key
CIHOLLKRGTVIJN-UHFFFAOYSA-N
Other Notes
This product has been replaced by 458139-ALDRICH | Luperox TBH70X, tert-Butyl hydroperoxide solution 70 wt. % in H2O
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signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. F - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
Storage Class
5.2 - Organic peroxides and self-reacting hazardous materials
wgk
WGK 3
flash_point_f
109.4 °F - closed cup
flash_point_c
43 °C - closed cup
Regulatory Information
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Yury Minko et al.
Nature protocols, 8(4), 749-754 (2013-03-23)
This protocol describes a new approach for the preparation of stereodefined trisubstituted chiral enolate species, avoiding conventional asymmetric enolization of carbonyl compounds. This protocol was developed as a single-flask synthetic sequence and therefore does not require isolation or purification of
Younghwa Kim et al.
Food chemistry, 137(1-4), 136-141 (2012-12-04)
Oligomeric and polymeric procyanidins have been reported to possess different antioxidant capacities. However, the intracellular antioxidant mechanisms of oligomeric and polymeric procyanidins are still poorly understood. In this study, we evaluated the cytoprotective effects of the oligomeric procyanidin fraction (OPF)
Qicai Xue et al.
Chemical communications (Cambridge, England), 49(35), 3700-3702 (2013-03-29)
A new synthetic approach toward direct C-N bond formation through sp(3) C-H activation has been developed under metal-free conditions. Both primary and secondary benzylic C-H substrates could react smoothly with various amines to give only mono-amination products with good to