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Merck
CN

CN205761

Palladium(II) nitrate hydrate

powder and chunks

Synonym(s):

Palladium dinitrate hydrate, Palladium nitrate hydrate, Palladous nitrate hydrate

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About This Item

Linear Formula:
Pd(NO3)2·xH2O
CAS Number:
Molecular Weight:
230.43 (anhydrous basis)
UNSPSC Code:
12161600
PubChem Substance ID:
MDL number:
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InChI

1S/2NO3.H2O.Pd/c2*2-1(3)4;;/h;;1H2;/q2*-1;;+2

SMILES string

O.[Pd++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI key

DTZRLFJKQHIVQA-UHFFFAOYSA-N

form

powder and chunks

Quality Level

reaction suitability

reaction type: Sonogashira Coupling, reagent type: catalyst
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst
core: palladium
reaction type: Heck Reaction, reagent type: catalyst
core: palladium
reaction type: Hiyama Coupling, reagent type: catalyst
core: palladium
reaction type: Negishi Coupling, reagent type: catalyst
core: palladium
reaction type: Stille Coupling, reagent type: catalyst
core: palladium
reaction type: Suzuki-Miyaura Coupling

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Application

Reactant for:
  • Preparation of platinum-palladium/carbon alloy nanocatalysts for methanol-tolerant oxygen reduction reaction in fuel cells
  • Synthesis of Cu-Pd alloy thin films on Ti substrates by co-electrodeposition of Pd and Cu from nitrate-base electrolytic baths
  • Preparation of palladium catalyst supported on vertically aligned multi-walled carbon nanotubes for microwave-assisted Heck reactions of p-iodonitrobenzene with styrene and Et acrylate
  • Preparation of a sinter-resistant Pd/SiO2 nanocatalyst
  • Preparation of di-phenyl sulfide-modified Pd/TiO2 catalysts for acetylene hydrogenation
  • Synthesis of alumina-supported palladium catalysts active for the gas phase hydrogenation of crotonaldehyde
Application
Catalyst for alkene nitration to glycol dinitrates; also used as a precursor to supported Pd catalysts.
Reactant for:
1. Preparation of platinum-palladium/carbon alloy nanocatalysts for methanol-tolerant oxygen reduction reaction in fuel cells
2. Synthesis of Cu-Pd alloy thin films on Ti substrates by co-electrodeposition of Pd and Cu from nitrate-base electrolytic baths
3. Preparation of palladium catalyst supported on vertically aligned multi-walled carbon nanotubes for microwave-assisted Heck reactions of p-iodonitrobenzene with styrene and Et acrylate
4. Preparation of a sinter-resistant Pd/SiO2 nanocatalyst
5. Preparation of di-phenyl sulfide-modified Pd/TiO2 catalysts for acetylene hydrogenation
6. Synthesis of alumina-supported palladium catalysts active for the gas phase hydrogenation of crotonaldehyde

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