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Merck
CN

CN299685

Palladium(II) trifluoroacetate

98%, solid

Synonym(s):

Pd(TFA)2, Trifluoroacetic acid palladium(II) salt

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About This Item

Linear Formula:
(CF3COO)2Pd
CAS Number:
42196-31-6
UNSPSC Code:
12161600
PubChem Substance ID:
24858054
NACRES:
NA.22
MDL number:
MFCD00013204

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InChI key

PBDBXAQKXCXZCJ-UHFFFAOYSA-L

InChI

1S/2C2HF3O2.Pd/c2*3-2(4,5)1(6)7;/h2*(H,6,7);/q;;+2/p-2

SMILES string

FC(F)(F)C(=O)O[Pd]OC(=O)C(F)(F)F

assay

98%

form

solid

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: C-H Activation, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

color

faint beige to very dark beige

Quality Level

200

General description

Palladium(II) trifluoroacetate is a catalyst used in Suzuki-Miyaura, Heck, and Stille cross-coupling reactions.

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions Catalyst used for the mild decarboxylation of electron-rich aromatic acidsand the direct cross-coupling of unactivated arenes.Catalyzes the selective allylic oxidation of geranylacetone and other olefins to their allyl acetates, which can then be converted to keto alcohols.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
WXBF7640V

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