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Merck
CN

02119

Sodium bromide

puriss., meets analytical specification of Ph. Eur., BP, USP, 99-100.5% (calc. to the dried substance)

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About This Item

Linear Formula:
NaBr
CAS Number:
Molecular Weight:
102.89
PubChem Substance ID:
eCl@ss:
38050404
UNSPSC Code:
12352302
EC Number:
231-599-9
MDL number:
Assay:
99-100.5% (calc. to the dried substance)
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InChI key

JHJLBTNAGRQEKS-UHFFFAOYSA-M

InChI

1S/BrH.Na/h1H;/q;+1/p-1

SMILES string

[Na+].[Br-]

vapor pressure

1 mmHg ( 806 °C)

grade

puriss.

assay

99-100.5% (calc. to the dried substance)

quality

meets analytical specification of Ph. Eur., BP, USP

impurities

acidity or alkalinity, complies, residual solvents, complies, ≤0.001% heavy metals (as Pb), ≤0.02% Mg, alkaline earth metals (as Ca)

loss

≤1% loss on drying, 120 °C

pH

5-7 (20 °C, 5%)

mp

755 °C (lit.)

anion traces

bromate (BrO3-): ≤10 mg/kg, chloride (Cl-): ≤2000 mg/kg, iodide (I-): ≤200 mg/kg, sulfate (SO42-): ≤50 mg/kg

cation traces

As: ≤2 mg/kg, Ba: ≤20 mg/kg, Ca: ≤50 mg/kg, Fe: ≤10 mg/kg, Mg: ≤10 mg/kg

suitability

complies for appearance of solution

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General description

Sodium bromide, an alkaline-earth halide, is an inorganic salt. Density, viscosity and electrolytic conductivity of concentrated aqueous solutions of alkaline-earth halides have been evaluated.

Application

Sodium bromide may be used in the following studies:
  • As catalyst for the microwave assisted three-component cyclocondensation of aryl aldehydes, alkyl nitriles and dimedone for the synthesis of highly functionalized tetrahydrobenzo[b]pyrans.
  • To compose the aqueous two-phase system (ATPS) containing Gemini surfactant ethanediyl-1,2-bis(dodecyldimethylammonium bromide).
  • Preparation of unoxidized and carboxylated pullulan, which are employed as mediators for the preparation of silver nanoparticles (AgNPs).

pictograms

Health hazardExclamation mark

signalword

Warning

Hazard Classifications

Repr. 2 - STOT RE 2 - STOT SE 3

target_organs

Central nervous system

flash_point_f

Not applicable

flash_point_c

Not applicable

Storage Class

11 - Combustible Solids

Regulatory Information

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Sodium bromide catalysed one-pot synthesis of tetrahydrobenzo [b] pyrans via a three-component cyclocondensation under microwave irradiation and solvent free conditions.
Devi I and Bhuyan PJ.
Tetrahedron Letters, 45(47), 8625-8627 (2004)
Sergiu Coseri et al.
Carbohydrate polymers, 116, 9-17 (2014-12-03)
Unoxidized and carboxylated pullulan (obtained by pullulan oxidation using TEMPO-sodium hypochlorite-sodium bromide system) have been used as mediators for the silver nanoparticles formation (AgNPs), under environment-friendly conditions: using aqueous solutions, room temperature and notably, by using both mediators as reducing
Ling Yue et al.
Applied biochemistry and biotechnology, 175(7), 3557-3570 (2015-02-05)
A novel aqueous two-phase system (ATPS) only containing Gemini surfactant ethanediyl-1,2-bis(dodecyldimethylammonium bromide) and an inorganic salt sodium bromide was designed, and the physicochemical properties of the ATPS were investigated systematically. The results have shown that the coexisting two phases, one
Density, viscosity, and electrolytic conductivity of concentrated aqueous electrolyte solutions at several temperatures. Alkaline-earth chlorides, lanthanum chloride, sodium chloride, sodium nitrate, sodium bromide, potassium nitrate, potassium bromide, and cadmium nitrate.
Isono T.
Journal of Chemical and Engineering Data, 29(1), 45-52 (1984)
Kajari Maiti et al.
The journal of physical chemistry. B, 114(22), 7499-7508 (2010-05-19)
Bolaforms B(1), B(2), and B(3) of the formulas, Br(-)Me(3)N(+)(CH(2))(10)N(+)Me(3)Br(-), Br(-)Me(3)N(+)(CH(2))(10)OH, and Br(-)Me(3)N(+)(CH(2))(10)COO(-)Na(+), respectively, were synthesized, and their properties in the bulk as well as at the air/aqueous NaBr (10 mM) solution interface have been studied. Their interactions with sodium dodecyl

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